Conventional dyeing processes currently practiced in the textile industry have a great environmental impact, mainly in relation to the quantity and pollution of water, use of toxic chemicals, atmospheric emissions, and high energy consumption. This study aims to discuss the relationship between the variables that involve conventional dyeing processes and environmental issues. It presents the mapping of the materials and emerging technologies for ecological coloration, specifically for the pretreatment and dyeing stages. Regarding pretreatment, it discusses biochemical (enzymes) and physical treatment (ultraviolet radiation, plasma, and ozone technology) approaches. With respect to the dyeing processes, it addresses ecological materials (natural dyes) and emerging technologies (such as plasma, supercritical CO2, AirDye®, ultrasonic, microwave, Nano-DyeTM, and electrochemical). Given the importance of ecological coloration, this study provides important reflections on the urgency of resolving issues related to barriers and economic viability in the implementation of the alternatives presented and demonstrates the need to develop educational projects to prepare fashion and textile professionals.
The E-Textile Swatch Exchange is a platform for sharing physical work samples in the field of electronic textiles. The exchange wishes to emphasize the importance of physicality and quality workmanship in an increasingly digital world. Individuals and collaborative efforts participate in the exchange by submitting a unique swatch design of their own, and in turn receive a compiled collection of everybody else's swatches. This means that everybody participating needs to make as many multiples of their swatch as the total number of participants. There are no guidelines defining what the swatches could or should be, only that they relate to the field of E-Textiles.
Reactions of 5-amino-alpha-imino-1H-imidazole-4-acetonitriles 1 with alkyl and aryl isocyanates led to efficient syntheses of 5'-amino-5-imino-4,4'-bi-1H-imidazol-2-ones 3 formed by intramolecular cyclization of the corresponding 5-amino-alpha-(N-alkyl/arylcarbamoyl)imino-1H-imidazole-4-acetonitriles 2. The cyclization occurs only slowly in solution but is considerably accelerated by the addition of a catalytic amount of DBU (1,8-diazabicyclo[5.4.0]undec-7-ene). The reaction of the N-arylamidine 6b, the synthetic precursor of the imidazole 1b, with benzyl isocyanate also led to the formation of 4,4'-bi-1H-imidazol-2-one 3b in quantitative yield. The imidazole intermediate 2b has been isolated and found to be identical with the compound obtained by reaction of the imidazole 1b and benzyl isocyanate. The N-arylamidine 6c (R = 4-NCC(6)H(4)) reacted with benzyl isocyanate in a similar way, but the electrophilicity of the amidine carbon atom resulted in rapid hydrolysis of the intermediate 7c leading ultimately to the isolation of the urea 9. The N-alkylamidines 6a and 6d behaved differently in their reaction with benzyl isocyanate, and the major product isolated in these reactions is again the urea 9.
Thermo-responsive Shape Memory Alloys are able to adopt a temporary configuration and return to their programmed shape when heated to a determined activation temperature. The possibility to integrate them in textile substrates creates potential to develop smart textiles whose shape change explores functional and expressive purposes. The aim of this research is to develop shape memory woven textiles in which dynamic behavior achieves predefined geometric shapes. The requirement of geometric morphology was addressed through origami techniques. Combining foldability properties with shape change, it is possible to design textile structures with a variable number of layers. Difference in light transmittance is analyzed according to layer variation. Experiments conducted explore methodological processes aimed at future developments in dynamic light filters research. The results highlight a process to design textiles with predefined geometric morphologies that can be activated electrically, and delineate a further study in order to improve the shape memory textile behavior.
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