The δ18O and δ13C (analyzed by isotope ratio mass spectrometry, IRMS) and concentration of 22 selected elements (analyzed by inductively coupled plasma—optical emission spectrometry, ICP-OES) in 190 Croatian microvinified and commercial wine samples from continental and coastal winegrowing areas and from three viticultural zones (B, CI, and CII) were measured to investigate whether multivariate statistical methods could provide the fingerprint for geographical origin determination. The highest power for discrimination of wines produced in Croatian winegrowing areas was achieved by general discriminant analysis (GDA) showing correct classification of 97.9% of all investigated samples, 100.0% of microvinified samples and 84.8% of commercial samples in the cross-validation matrix. The most significant markers for discrimination of coastal and continental areas found by GDA were δ18O and Co, followed by K, Rb, Sn, Li, and δ13C in descending order. GDA showed higher levels of correctly classified samples from three viticultural zones in Croatia if only microvinified samples were employed in the analysis (94.9%) than for all samples together (86.3%) or for commercial samples (66.1%) in the cross-validation matrix. The discrimination of viticultural zones B, CI, and CII in Croatia was achieved by δ18O, Co, Rb, Li, K, and Sn. The results obtained showed that the relationships between the isotopic ratios and concentrations of different considered elements combined with appropriate statistical model represent a powerful tool in discrimination of wines produced in different Croatian winegrowing areas.
Miscanthus × giganteus (Greef et Deu) is an agro-energy crop of the second generation cultivated in purpose to obtain annually renewable bio-fuel produced from the aboveground biomass. Cultivation is preferred on marginal lands to avoid occupation of arable lands. Influence of fertilization and soil type Gleysol, Planosol and Technosol (open pit coal mine overburden) on yield and biomass traits of miscanthus were investigated during five years’ field experiment. Among biometric characteristics: stem height, length and width of leaves, the number of leaves (dry and green) per stem and number of stems per rhizome, only the last one has a strong positive correlation with yield. Fertilization increased yield during fourth and fifth year of development on Gleysol and Technosol. The highest yield on Gleysol was 23.12 t/ha in 2014, on Planosol 10.16 t/ha, and 4.77 t/ha in 2015 on Technosol. The yield of miscanthus, beside fertilization, depends on weather conditions and weeds. Cultivation of miscanthus is possible on marginal soils with minimum application of agricultural measures only in the year of establishment. Gleysol is a type of soil that can be recommended for miscanthus cultivation.
The aim of this work was to classifie vine growing regions of Croatia using bioclimatic indices. For the analysis of climatic conditions, linear trends of bioclimatic indices were determined using meteorological observations for all avaliable climatological stations located in vine growing regions of Croatia. Analysis were performed for two different climatological periods: 1961-1990 and 1988-2017. Four commonly used bioclimatic indices were determined: the Winkler index, the Huglin index, Cool night index and Growing season average temperature.
Agro-energy crop, Miscanthus × giganteus should be produced on marginal land in order to avoid land suitable for food production. Production of electricity in thermal power plants occupies large land areas by depositing tailings from surface mines, and depositing ash and slag. During the first year of Miscanthus × giganteus growing in containers, the concentration of heavy metals: As, Cd, Co, Cr, Cu, Mn, Ni, Pb, Zn and Fe was monitored in underground and aboveground plant parts. The substrate was overburden from open pit coal mine RB Kolubara and ash from TPP Nikola Tesla B. Significant differences were found between the substrate and the investigated elements, but in all cases the accumulated heavy metals almost completely remained stable in underground organs of plant. It can be concluded that biomass of Miscanthus × giganteus could be used as energy source if it is grown on a soil moderately contaminated by heavy metals.
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