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In the process of lead production from leadbearing materials generated in copper metallurgy, a large amount of hazardous waste in the form of slag is produced. To assess the effect of the slag on the environment, its physicochemical properties were determined. In this study, the following methods were used: wavelength dispersive X-ray fluorescence (WD XRF), X-ray diffraction (XRD), and Bunte-Baum-Reerink method to determine softening and melting points, as well as viscosity examination and leaching tests. The measurements were performed on the slag produced with two different amounts of iron addition to the lead smelting process. The resulting slags, an oxide rich phase slag and a sulfide rich phase slag have different compositions and physicochemical properties. It was found that the increase in iron addition causes an increase in the softening melting point of the oxide rich phase slag by about 100°C, and a twofold increase in the viscosity of both slag phases. The increase in iron addition also results in the decrease in As leachability and increase in Zn, Fe, and Cu leachability from the slags. Slag produced with increased iron addition has a greater impact on the environment.

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Purpose The purpose of this study is application of a numerical simulation for determination of the influence of geometric parameters of a furnace and hydrodynamics of the gas introduced by a vertical submerged lance on the process of feed mixing and temperature distribution. Design/methodology/approach A numerical simulation with Phoenics software was applied for modeling of liquid phase movement and heat exchange between the gas supplied through a lance and the slag feed in a top submerged lance (TSL) furnace. The simulation of a two-phase flow of a slag–gas mixture based on the inter phase slip algorithm module was conducted. The influence of selected parameters, such as depth of lance submergence, gas flow rate and change of furnace geometry, on the phenomena of movement was studied. Findings Growth of dynamics of mixing with the depth of lance submergence and with increase of gas velocity in the lance was observed. Formation of a recirculation zone in the liquid slag was registered. Movement of the slag caused by the gas flow brought homogenization of the temperature field. Originality/value The study applied the simulation of a two-phase flow in the liquid slag–gas system in steady state, taking into account heat transfer between phases. It provides possibilities for optimization and selection of process parameters within the scope of the developed new technology using a TSL furnace.

Process of heat exchange in a rotary furnace during converter slag reduction was modelled.Temperature distribution in the furnace and temperature of the charge (slag) only were examined. Influence of modification of the process gas supply method by changing the number of nozzles on the course of the reduction process was analyzed. It has been found out that application of a nozzle as a submerged flame burner provides possibilities to reach higher charge temperature. Application of more nozzles in the process of converter slag reduction can increase temperature of reduced slag and provide better uniformity of charge heating.