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The sonochemical reaction of Fe(CO)5 and triethylphosphine has been found to produce solid amorphous iron phosphide of composition FeP. The resulting compound was characterized by elemental microanalysis, scanning electron microscopy, energy-dispersive X-ray analysis, and Debye-Scherrer powder X-ray diffraction. X-ray powder patterns were obtained after the amorphous material had been heated above 950 degrees C and then slowly cooled to induce crystallization. This reaction provides the first use of ultrasound to sonochemically synthesize amorphous phosphide semiconductor materials from organometallic precursors.

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An energy-dispersive X-ray (EDX) study of binary mixtures of mixed composition metal powders exposed to high-intensity ultrasound in decane indicates that metal particles are fused by the action of ultrasound and develop intermetallic coatings. The principal mechanism behind both processes is interparticle collision caused by the rapid movement of particles propelled by shockwaves generated at cavitation sites. By examination of systems with differing metallurgical compatibilities (Ni/Co, Cu/Cr, and Cu/Mo), it has been determined that the intermetallic coatings are generated by both adhesive wear and direct impact. The mechanisms of ultrasound-induced coatings are discussed.

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