The title compound, C11H9N3O2, exists in the E conformation with respect to the azomethane C=N bond, and has the keto form. There are two independent molecules in the asymmetric unit and each of these features a slight slanting of the pyridine and furan rings, which form a dihedral angle of 14.96 (10)° in one of the molecules and 5.53 (10)° in the other. The crystal structure is stabilized by N—H⋯O and N—H⋯N hydrogen bonds, weak C—H⋯O and C—H⋯N hydrogen bonds and C—H⋯π interactions and π–π interactions [shortest centroid–centroid distance = 3.7864 (15) Å].
The title compound, C15H13BrN2O3·H2O, exists in an E conformation with respect to the azomethane C=N double bond. The benzene and phenyl rings form dihedral angles of 0.46 (2) and 4.90 (3)°, respectively with the central C(=O)N2C unit. An intramolecular O—H⋯N hydrogen bond occurs. In the crystal, some hydrazide molecules are replaced by molecules of the 6-bromo isomer. The Br atom from this admixture was refined to give a partial occupancy of 0.0443 (19). A supramolecular network is built in the lattice by means of intermolecular N—H⋯O and two O—H⋯O interactions together with non-classical C—H⋯O interactions involving the lattice water molecule stacking the molecules along the b-axis direction.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.