The desorption of molecular species from ice mantles back into the gas phase in molecular clouds results from a variety of very poorly understood processes. We have investigated three mechanisms: desorption resulting from H 2 formation on grains, direct cosmic ray heating and cosmic ray-induced photodesorption. Whilst qualitative differences exist between these processes (essentially deriving from the assumptions concerning the species selectivity of the desorption and the assumed threshold adsorption energies, E t ), all the three processes are found to be potentially very significant in dark cloud conditions. It is therefore important that all three mechanisms should be considered in studies of molecular clouds in which freeze-out and desorption are believed to be important. Employing a chemical model of a typical static molecular core and using likely estimates for the quantum yields of the three processes, we find that desorption by H 2 formation probably dominates over the other two mechanisms. However, the physics of the desorption processes and the nature of the dust grains and ice mantles are very poorly constrained. We therefore conclude that the best approach is to set empirical constraints on the desorption, based on observed molecular depletions -rather than try to establish the desorption efficiencies from purely theoretical considerations. Applying this method to one such object (L16 89B) yields upper limits to the desorption efficiencies that are consistent with our understanding of these mechanisms.

We present observations of the rotational ortho-water ground transition, the two lowest para-water transitions, and the ground transition of ionised ortho-water in the archetypal starburst galaxy M 82, performed with the HIFI instrument on the Herschel Space Observatory. These observations are the first detections of the para-H 2 O(1 11 -0 00 ) (1113 GHz) and ortho-H 2 O + (1 11 -0 00 ) (1115 GHz) lines in an extragalactic source. All three water lines show different spectral line profiles, underlining the need for high spectral resolution in interpreting line formation processes. Using the line shape of the para-H 2 O(1 11 -0 00 ) and ortho-H 2 O + (1 11 -0 00 ) absorption profile in conjunction with high spatial resolution CO observations, we show that the (ionised) water absorption arises from a ∼2000 pc 2 region within the HIFI beam located about ∼50 pc east of the dynamical centre of the galaxy. This region does not coincide with any of the known line emission peaks that have been identified in other molecular tracers, with the exception of HCO. Our data suggest that water and ionised water within this region have high (up to 75%) area-covering factors of the underlying continuum. This indicates that water is not associated with small, dense cores within the ISM of M 82 but arises from a more widespread diffuse gas component.

The Gould Belt Legacy Survey will map star-forming regions within 500 pc, using HARP (Heterodyne Array Receiver Programme), SCUBA-2 (Submillimetre Common-User Bolometer Array 2) and POL-2 (Polarimeter 2) on the James Clerk Maxwell Telescope (JCMT). This paper describes HARP observations of the J = 3-2 transitions of 13CO and C18O towards Orion A. The 1500-resolution observations cover 5 pc of the Orion filament, including OMC1 (inc. BN-KL and Orion Bar), OMC 2/3 and OMC 4, and allow a comparative study of the molecular gas properties throughout the star-forming cloud. The filament shows a velocity gradient of ~1 km/s /pc between OMC 1, 2 and 3, and high velocity emission is detected in both isotopologues. The Orion Nebula and Bar have the largest masses and line widths, and dominate the mass and energetics of the high velocity material. Compact, spatially resolved emission from CH3CN, 13CH3OH, SO, HCOOCH3, C2H5OH, CH3CHO and CH3OCHO is detected towards the Orion Hot Core. The cloud is warm, with a median excitation temperature of ~24 K; the Orion Bar has the highest excitation temperature gas, at >80 K. The C18O excitation temperature correlates well with the dust temperature (to within 40%). The C18O emission is optically thin, and the 13CO emission is marginally optically thick; despite its high mass, OMC 1 shows the lowest opacities. A virial analysis indicates that Orion A is too massive for thermal or turbulent support, but is consistent with a model of a filamentary cloud that is threaded by helical magnetic fields. The variation of physical conditions across the cloud is reflected in the physical characteristics of the dust cores....continue

???The definitive version is available at www3.interscience.wiley.com '. Copyright Royal Astronomical Society.The Gould Belt Legacy Survey will survey nearby star-forming regions (within 500 pc), using Heterodyne Array Receiver Programme (HARP), Submillimetre Common-User Bolometer Array 2 and Polarimeter 2 on the James Clerk Maxwell Telescope. This paper describes the initial data obtained using HARP to observe 12CO, 13CO and C18O J= 3 ??? 2 towards two regions in Orion B, NGC 2024 and NGC 2071. We describe the physical characteristics of the two clouds, calculating temperatures and opacities utilizing all the three isotopologues. We find good agreement between temperatures calculated from CO and from dust emission in the dense, energetic regions. We determine the mass and energetics of the clouds, and of the high-velocity material seen in 12CO emission, and compare the relative energetics of the high- and low-velocity material in the two clouds. We present a clumpfind analysis of the 13CO condensations. The slope of the condensation mass functions, at the high-mass ends, is similar to the slope of the initial mass function

The definitive version is found at: http://onlinelibrary.wiley.com Copyright Royal Astronomical SocietyThe Gould Belt Legacy Survey on the James Clerk Maxwell Telescope's has observed a region of 260 arcmin2 in 12CO J = 3 -> 2 emission, and a 190 arcmin2 subset of this in 13CO and C18O towards the Serpens molecular cloud. We examine the global velocity structure of the non-outflowing gas, and calculate excitation temperatures and opacities. The large-scale mass and energetics of the region are evaluated, with special consideration for high-velocity gas. We find the cloud to have a mass of 203 M-circle dot, and to be gravitationally bound, and that the kinetic energy of the outflowing gas is approximately 70 per cent of the turbulent kinetic energy of the cloud. We identify compact outflows towards some of the submillimetre Class 0/I sources in the region