A new, rapid air sampling/sample preparation methodology was investigated using adsorptive solid-phase microextraction (SPME) fiber coatings and nonequilibrium conditions for volatile organic compounds (VOCs). This method is the fastest extraction technique for air sampling at typical airborne VOC concentrations. A theoretical model for the extraction was formulated based on the diffusion through the interface between the sampled (bulk) air and the SPME coating. Parameters that affect the extraction process including sampling time, air velocity, air temperature, and relative humidity were investigated with the porous (solid) PDMS/DVB and Carboxen/PDMS coatings. Very short sampling times from 5 s to 1 min were used to minimize the effects of competitive adsorption and to calibrate the extraction process in the initial linear extraction region. The predicted amounts of extracted mass compared well with the measured amounts of target VOCs. Findings presented in this study extend the existing fundamental knowledge related to sampling/sample preparation with SPME, thereby enabling the development of new sampling devices for the rapid sampling of air, headspace, water, and soil.

The Geological Survey of Norway (NGU) has produced new aeromagnetic and gravity maps from Norway and adjacent areas, compiled from ground, airborne and satellite data. Petrophysical measurements on core samples, hand specimens and on in situ bedrock exposures are essential for the interpretation of these maps. Onshore, the most prominent gravity and magnetic anomalies are attributed to lower crustal rocks that have been brought closer to the surface. The asymmetry of the gravity anomalies along the Lapland Granulite Belt and Kongsberg–Bamble Complex, combined with the steep gradient, points to the overthrusted high-density granulites as being the main source of the observed anomalies. The Kongsberg–Bamble anomaly can be traced southwards through the Kattegat to southern Sweden. This concept of gravity field modelling can also be applied to the Mid-Norwegian continental shelf and could partially explain the observed high-density rocks occurring below the Møre and Vøring basins and in the Lofoten area. Extrapolations of Late-Caledonian detachment structures occurring on the mainland can be traced on aeromagnetic and gravimetric images towards the NW across the continental margin. Subcropping Late Palaeozoic to Cenozoic sedimentary units along the mid-Norwegian coast produce a conspicuous magnetic anomaly pattern. The asymmetry of the low-amplitude anomalies, with a steep gradient and a negative anomaly to the east and a gentler gradient to the west, relates the anomalies to gently westward dipping strata. Recent aeromagnetic surveys in the Barents Sea have revealed negative magnetic anomalies associated with shallow salt diapirs. Buried Quaternary channels partly filled with gravel and boulders of crystalline rocks generate magnetic anomalies in the North Sea. The new maps also show that the opening of the Norwegian–Greenland Sea occurred along stable continental margins without offsets across minor fracture zones, or involving jumps in the spreading axis. A triple junction formed at 48 Ma between the Lofoten and Norway Basins.

Odor profiling efforts were directed at applying to high-density livestock operations some of the lessons learned in resolving past, highly diverse, odor-focused investigations in the consumer product industry. Solid-phase microextraction (SPME) was used for field air sampling of odorous air near and downwind of a beef cattle feedyard and a swine finisher barn in Texas. Multidimensional gas chromatography-olfactometry (MDGC-O) was utilized in an attempt to define and prioritize the basic building blocks of odor character associated with these livestock operations. Although scores of potential odorant volatiles have been previously identified in high-density livestock operations, the odor profile results developed herein suggest that only a very few of these may constitute the preponderance of the odor complaints associated with these environments. This appeared to be especially true for the case of increasing distance from both cattle feedyard and swine barn facilities, with p-cresol consistently taking on the dominant odor impact role with ever increasing distance. In contrast, at- or near-site odor profiles were shown to be much more complex, with many of the well-known lower tier odorant compounds rising in relative significance. For the cattle feedyard at- or near-site odor profiles, trimethylamine was shown to represent a significantly greater individual odor impact relative to the more often cited livestock odorants such as hydrogen sulfide, the organic sulfides, and volatile fatty acids. This study demonstrates that SPME combined with a MDGC-O-mass spectrometry system can be used for the sampling, identification, and prioritization of odors associated with livestock.

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