Transpiration
is the process by which water is carried in plants from the roots
to the leaves where evaporation takes place. Here, we report a transpiration
driven electrokinetic power generator (TEPG) that exploits capillary
flow of water in an asymmetrically wetted cotton fabric coated with
carbon black. Accumulation of protons induced by the electrical double
layer formed at the solid (carbon black)/liquid (water) interface
gives rise to potential difference between the wet and dry sides.
The conductive carbon black coating channels electrical current driven
by the pseudostreaming mechanism. A TEPG of 90 mm × 30 mm ×
0.12 mm yields a maximum voltage of 0.53 V, maximum current of 3.91
μA, and maximum energy density of 1.14 mWh cm–3, depending on the loading of the carbon black. Multiple TEPGs generate
enough power to light up a light-emitting diode (20 mA × 2.2
V) or charge a 1 F supercapacitor.
The artificial hydrological cycle built by using deliquescent calcium chloride enables self-operation of a transpiration-driven electrokinetic power generator.
Nano-hydroelectric technology utilizes hydraulic flow through electronically conducting nanomaterials to generate electricity in a simple, renewable, ubiquitous, and environmentally friendly manner. Up to date, several designs of nano-hydroelectric devices have...
Catalysis with single-atom
catalysts (SACs) exhibits outstanding
reactivity and selectivity. However, fabrication of supports for the
single atoms with structural versatility remains a challenge to be
overcome, for further steps toward catalytic activity augmentation.
Here, we demonstrate an effective synthetic approach for a Pt SAC
stabilized on a controllable one-dimensional (1D) metal oxide nano-heterostructure
support, by trapping the single atoms at heterojunctions of a carbon
nitride/SnO2 heterostructure. With the ultrahigh specific
surface area (54.29 m2 g–1) of the nanostructure,
we obtained maximized catalytic active sites, as well as further catalytic
enhancement achieved with the heterojunction between carbon nitride
and SnO2. X-ray absorption fine structure analysis and
HAADF-STEM analysis reveal a homogeneous atomic dispersion of Pt species
between carbon nitride and SnO2 nanograins. This Pt SAC
system with the 1D nano-heterostructure support exhibits high sensitivity
and selectivity toward detection of formaldehyde gas among state-of-the-art
gas sensors. Further ex situ TEM analysis confirms
excellent thermal stability and sinter resistance of the heterojunction-immobilized
Pt single atoms.
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