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Current approaches to tailoring the thermal expansion coefficient of materials or finding materials with negative thermal expansion rely on careful manipulation of either the material's composition and/or the complex fabrication of composites. Here, by contrast, we report a new principle that enables the precise control of macroscopic thermal expansion response of bulk materials via crystallographic texture manipulation and by taking advantage of anisotropic Coefficients of Thermal Expansion (CTE) in a large class of martensitically transforming materials. Through simple thermo-mechanical processing, it is possible to tailor the thermal expansion response of a single material-without manipulating its composition-over a wide range of positive and negative values. We demonstrate this principle by gradually tuning the macroscopic CTE in a model NiTiPd alloy between a positive (+14.90×10−6 −1) and a negative (−3.06×10−6 −1) value, simply by incrementally increasing tensile plastic deformation in the martensite phase. This surprising response is linked to the large positive, +51.33×10−6K−1, and negative, −34.51×10−6K−1, CTE anisotropy, at the lattice level, along the different crystal directions in martensite. Similar CTE anisotropy is also shown experimentally in CoNiGa and TiNb alloys. In a model TiNb alloy, giant macroscopic CTEs of +181×10−6 −1 and −142×10−6 −1 are measured. A connection between the CTE anisotropy and the martensitic transformation in these and other materials systems such as NiTi, pure uranium, and PbTiO 3 is later made. It is shown that negative or positive thermal expansion crystallographic directions are connected to the crystallographic relationship between the austenite and martensite lattices, and can easily be predicted using the lattice parameters of austenite and martensite phases. Our current observations and analyses suggest that the tunability of the macroscopic CTE through thermo-mechanical processing is universal in materials-both ceramic and metals-that undergo martensitic transformations.

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Structural glasses are characterized by the loss of long-range translational and rotational symmetry. In the last two decades, however, it has been discovered that materials that exhibit ferroic (ferromagnetic, ferroelectric and ferroelastic) phase transformations may also exhibit glassy behavior, in which the ferroic degrees of freedom (magnetization, polarization, strain) exhibit a loss of long-range translational symmetry. A consequence of this loss of longrange symmetry is the suppression of the ferroic phase transitions. Moreover, these unique glassy systems exhibit dynamic and thermodynamic behavior analogous to regular structural glasses.Conventionally, the onset of glassy behavior is brought about by the introduction of spatial heterogeneities, typically originating from point defects, particularly in the case of strain glasses.Here, we demonstrate, for the first time, that configurational order/disorder in a single ferromagnetic alloy (Ni 45 Co 5 Mn 36.6 In 13.4 ) can be used to stabilize both strain and magnetic glasses. The control of the degree of configurational order--through simple heat treatment schedules--, and simultaneous application of stress and magnetic field enabled us to observe a Kauzmman point, that is, the collapse of the entropy difference between a crystalline and a glassy phase. Systematic investigation of the transformation behavior in this system as a function of heat treatment enabled us to observe four kinds of solid-solid phase transitions (ferromagnetic-paramagnetic, martensitic transformation, strain and magnetic glass) in a single composition. The alloy investigated can be used to further elucidate the nature of ferroic glass transitions and their coupling.

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