The application of bio-based materials is becoming impellent owing to the increasing demand for alternatives to petroleum-based analogs. In this regard, cellulose nanocrystals (CNCs) with unique properties have received a significant interest, while their hydrophilic character poses a challenge to their commercial applications. Ultrasonication treatment is one of the most commonly used methods to improve CNCs' dispersion in different solvents and polymer matrices. In this work, the effectiveness of ultrasonication treatment in the dispersion of CNCs in a water-soluble polymer (polyvinyl alcohol, PVA) was studied. An aqueous suspension of polyvinyl alcohol and CNCs was prepared using different ultrasonication times and amplitudes. The morphology, particle size and dispersion of CNCs were studied using X-ray diffraction, transmission electron microscopy, and dynamic light scattering. The results indicated that with increase in the sonication amplitude, there was a substantial decrease in nanoparticle length, while long sonication times gently affected the nanoparticle length. Furthermore, improved dispersion was observed in samples prepared using longer sonication time.
Biopolymers are an emerging class of materials being widely pursued due to their ability to degrade in short periods of time. Understanding and evaluating the recyclability of biopolymers is paramount for their sustainable and efficient use in a cost-effective manner. Recycling has proven to be an important solution, to control environmental and waste management issues. This paper presents the first recycling assessment of Solanyl, Bioflex, polylactic acid (PLA) and PHBV using a melt extrusion process. All biopolymers were subjected to five reprocessing cycles. The thermal and mechanical properties of the biopolymers were investigated by GPC, TGA, DSC, mechanical test, and DMA. The molecular weights of Bioflex and Solanyl showed no susceptible effect of the recycling process, however, a significant reduction was observed in the molecular weight of PLA and PHBV. The inherent thermo-mechanical degradation in PHBV and PLA resulted in 20% and 7% reduction in storage modulus, respectively while minimal reduction was observed in the storage modulus of Bioflex and Solanyl. As expected from the Florry-Fox equation, recycled PLA with a high reduction in molecular weight (78%) experienced 9% reduction in glass transition temperature. Bioflex and Solanyl showed 5% and 2% reduction in molecular weight and experienced only 2% reduction in glass transition temperature. These findings highlight the recyclability potential of Bioflex and Solanyl over PLA and PHBV.
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