Oxygen incorporation from CO(2) into Fe-doped SrTiO(3)(100) single crystals (0.013 at% Fe, 0.039 at% Fe and 0.13 at% Fe) was investigated. Oxygen incorporation processes using (13)C(18)O(2) as the gas source were studied by isotope exchange depth profiling (IEDP) and subsequent secondary-ion mass spectroscopy (SIMS). The interaction of CO(2) with SrTiO(3) (100) surfaces was further studied with different surface analytical techniques like metastable induced electron spectroscopy (MIES), ultraviolet photoelectron spectroscopy (UPS) and X-ray photoelectron spectroscopy (XPS). Results indicate that CO(2) interaction with SrTiO(3) (100) surfaces does not change the surface at all. It seems that CO(2) provides a very low sticking probability on the surface as it is not traced by valence band spectroscopy even at room temperature. Nonetheless, (13)C(18)O(2) acts as an incorporation source of (18)O into the Fe-doped SrTiO(3) single crystals. The diffusion coefficient exhibits a peculiar behaviour when Fe concentration increases. No carbon incorporation is observed at all.

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Ionic Liquids (IL) are novel materials with a wide range of applications. The variable combination of organic cation and inorganic anion offers the possibility of tuning their properties. In the present investigation we test the application of different ionic liquids as charging agents for the preparation of stable oxide suspensions for direct use in electrophoretic deposition to produce oxide layers on different substrates. Main objective of these investigations was to prove that this substance class constitutes suitable additives for successful electrophoretic deposition (EPD). As one key parameter for the EPD process is the particle charge, a big part of our investigations involved the measurement of the zeta-potential of in alcoholic suspension under the influence of phosphonium and imidazolium based ionic liquids using a micro-electrophoresis measurement