Thermoelectric materials are special types of semiconductors that function as "heat pumps" and as heat-to-electricity converters. Thermoelectric power generation allows for small size, high reliability, and quiet operation. Efficient thermoelectric-based heat-to-electricity converters require higher performance materials than are currently available.[1, 2] Direct conversion of heat to electricity could be achieved with solidstate devices based on thermoelectric materials. These devices could play an important role in future energy production, conversion, management, and utilization. When a temperature gradient is created across a thermoelectric

The series of Pb(9.6)Sb(0.2)Te(10)(-)(x)Se(x) compounds with different Se content (x) were prepared, and their structure was investigated at the atomic and nanosized regime level. Thermoelectric properties were measured in the temperature range from 300 to 700 K. The Pb(9.6)Sb(0.2)Te(10)(-)(x)Se(x) series was designed after the refinement of the single-crystal structure of Pb(3.82)Sb(0.12)Te(4) (Pb(9.6)Sb(0.3)Te(10); S.G. Pmm) by substituting isoelectronically in anion positions Te by Se. The Pb(9.6)Sb(0.2)Te(10)(-)(x)Se(x)() compounds show significantly lower lattice thermal conductivity (kappa(L)) compared to the well-known PbTe(1)(-)(x)Se(x) solid solutions. For Pb(9.6)Sb(0.2)Te(3)Se(7) (x = 7), a kappa(L) value as low as 0.40 W/m.K was determined at 700 K. High-resolution transmission electron microscopy of several Pb(9.6)Sb(0.2)Te(10)(-)(x)Se(x) samples showed widely distributed Sb-rich nanocrystals in the samples which is the key feature for the strong reduction of the lattice thermal conductivity. The reduction of kappa(L) results in a significantly enhanced thermoelectric figure of merit of Pb(9.6)Sb(0.2)Te(10)(-)(x)Se(x) compared to the corresponding PbTe(1)(-)(x)Se(x) solid solution alloys. For Pb(9.6)Sb(0.2)Te(3)Se(7) (x = 7), a maximum figure of merit of ZT approximately 1.2 was obtained at approximately 650 K. This value is about 50% higher than that of the state-of-the-art n-type PbTe. The work provides experimental validation of the theoretical concept that embedded nanocrystals can promote strong scattering of acoustic phonons.

Thermoelectric materials are special types of semiconductors that function as "heat pumps" and as heat-to-electricity converters. Thermoelectric power generation allows for small size, high reliability, and quiet operation. Efficient thermoelectric-based heat-to-electricity converters require higher performance materials than are currently available.[1, 2] Direct conversion of heat to electricity could be achieved with solidstate devices based on thermoelectric materials. These devices could play an important role in future energy production, conversion, management, and utilization. When a temperature gradient is created across a thermoelectric

Ag1- x SnSb1+ x Te3 presents a rare combination of large positive thermoelectric power response coexisting with an almost metallic carrier concentration. It is proposed that this unusual state arises from a high effective mass for the hole carriers which may derive from nanostructuring in the material.