The known silatranes have attached substituents such as hydrogen, organyl, organoxy, aminoalkyl, thioorganyl, acyloxy, halogen, pseudohalogen, and other groups; however, their functionalization with any polycyclic aromatic hydrocarbon substituent is not recognized; this creates a niche in silatrane chemistry.

Excess of Al(III) is considered as toxic for living organisms. By keeping harmful effects of Al(III) in mind, a new Schiff base functionalized silatrane as a potential Chemo-sensor for the...

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The o-, m- and p-isomeric units of chalconyl triazole-based, caged organosilicon complexes were efficiently synthesized and explored for their cationic chemosensing activities.