We present a new concept for the detection of hydrogen sulfide (H2S) doses based on percolation effects in semiconducting (p‐type) copper (II) oxide (CuO) thin films. Under H2S exposure at 180 °C CuO undergoes a chemical reaction to metallic conducting copper (II) sulfide (CuS). Reaching a certain dose of H2S (concentration × exposure time) the conductance increases rapidly by two orders of magnitude which is attributed to the formation of CuS percolation paths. This study focuses on the reproducibility of this effect as well as on theoretical modeling of the assumed underlying percolation mechanism. Analysis of conductance data reveals a behavior that is qualitatively very similar to standard scaling theory, but with a lower conductance exponent of µ ≈ 0.85 (instead of 1.3 for 2D systems). The deviation can be explained by a superimposing diffusion process and by deviations of the experimental systems from standard percolation systems. Nevertheless, the CuO thin films exhibit intrinsic structure controlled thresholds for H2S doses, which allows the utilization as H2S dosimeter.
Conductance behavior of a CuO thin film exposed to 20 ppm H2S at 180 °C. The percolation threshold pc is reached 1054 s after start of the measurement.
The inverse transfer of magnetic helicity is studied through a fourth-order finite volume numerical scheme in the framework of compressible ideal magnetohydrodynamics (MHD), with an isothermal equation of state. Using either a purely solenoidal or purely compressive mechanical driving, a hydrodynamic turbulent steady-state is reached, to which small-scale magnetic helical fluctuations are injected. The steady-state root mean squared Mach numbers considered range from 0.1 to about 11. In all cases, a growth of magnetic structures is observed. While the measured magnetic helicity spectral scaling exponents are similar to the one measured in the incompressible case for the solenoidally-driven runs, significant deviations are observed even at relatively low Mach numbers when using a compressive driving. A tendency towards equipartition between the magnetic and kinetic fields in terms of energy and helicity is noted. The joint use of the helical decomposition in the framework of shell-to-shell transfer analysis reveals the presence of three distinct features in the global picture of a magnetic helicity inverse transfer. Those are individually associated with specific scale ranges of the advecting velocity field and commensurate helical contributions.
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