The inhibitory behaviour of non-ionic sugar based N,N′-didodecyl-N,N′-digluconamideethylenediamine gemini surfactant, designated as Glu(12)-2-Glu(12) on mild steel (MS) corrosion in 3.5% NaCl at 30–60 °C was explored using weight loss, PDP, EIS and SEM/EDAX/AFM techniques. The compound inhibited the corrosion of mild steel in 3.5% NaCl and the extent of inhibition was dependent on concentration and temperature. The inhibiting action of Glu(12)-2-Glu(12) is synergistically enhanced on addition of potassium iodide (KI) at all concentrations and temperatures. The inhibiting formulation comprising of 2.5 × 10−3 mM of Glu(12)-2-Glu(12) and 10 mM of KI exhibits an inhibition efficiency of 96.9% at 60 °C. Quantum chemical calculations and MD simulation were applied to analyze the experimental data and elucidate the adsorption behaviour and inhibition mechanism of inhibitors. MD simulation showed a nearly parallel or flat disposition for Glu(12)-2-Glu(12) molecules on the MS surface providing larger blocking area to prevent the metal surface from corrosion.
This review article summarizes the development of different kinds of materials that evolved interest in all field of science particularly on new nano-materials which possess both electric and magnetic properties at the nanoscale. Materials of such kind possessing both magnetic and electric properties have tremendous applications and own an intensive research activity. These materials induce new properties which are particularly important in electronic and magnetic devices and even in the materials where magnetic property will change by electric field or vice versa. The discovery of such ferroic properties for scientific applications is the need of hour and spreads an exciting new area that has technical and commercial potential for the discovery of advanced materials. In recent studies, the actual path by which the multiferroic properties exist has been focused and new metal oxide compounds were discovered. The understanding of the structure of these compounds through research describes a wide range of applications and the challenges of these multiferroic materials that need to be explored. In this study, fundamental aspects and structural variations of ternary transition metal oxides have been covered which possess novel properties in storage devices such as hard disk platters and magnetic read heads.
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