Abstract. Stratosphere-to-troposphere transport (STT) provides an important natural source of ozone to the upper troposphere, but the characteristics of STT events in the Southern Hemisphere extratropics and their contribution to the regional tropospheric ozone budget remain poorly constrained. Here, we develop a quantitative method to identify STT events from ozonesonde profiles. Using this method we estimate the seasonality of STT events and quantify the ozone transported across the tropopause over Davis (69 • S, 2006Davis (69 • S, -2013, Macquarie Island (54 • S, 2004-2013), and Melbourne (38 • S, 2004-2013). STT seasonality is determined by two distinct methods: a Fourier bandpass filter of the vertical ozone profile and an analysis of the Brunt-Väisälä frequency. Using a bandpass filter on 7-9 years of ozone profiles from each site provides clear detection of STT events, with maximum occurrences during summer and minimum during winter for all three sites. The majority of tropospheric ozone enhancements owing to STT events occur within 2.5 and 3 km of the tropopause at Davis and Macquarie Island respectively. Events are more spread out at Melbourne, occurring frequently up to 6 km from the tropopause. The mean fraction of total tropospheric ozone attributed to STT during STT events is ∼ 1.0-3.5 % at each site; however, during individual events, over 10 % of tropospheric ozone may be directly transported from the stratosphere. The cause of STTs is determined to be largely due to synoptic low-pressure frontal systems, determined using coincident ERA-Interim reanalysis meteorological data. Ozone enhancements can also be caused by biomass burning plumes transported from Africa and South America, which are apparent during austral winter and spring and are determined using satellite measurements of CO. To provide regional context for the ozonesonde observations, we use the GEOS-Chem chemical transport model, which is too coarsely resolved to distinguish STT events but is able to accurately simulate the seasonal cycle of tropospheric ozone columns over the three southern hemispheric sites. Combining the ozonesonde-derived STT event characteristics with the simulated tropospheric ozone columns from GEOS-Chem, we estimate STT ozone flux near the three sites and see austral summer dominated yearly amounts of between 5.7 and 8.7 × 10 17 molecules cm −2 a −1 .

The response of atmospheric composition to ongoing environmental change remains poorly constrained across much of the Southern Hemisphere. We use a 20‐year record of ground‐based total column measurements from Wollongong, southeast Australia to identify a statistically significant decreasing trend in formaldehyde of −1.9 [−2.2, −1.7]%/year. The trend is consistently negative across all months except November. Satellite data indicate that the trend at Wollongong is distinctly local and is superimposed on a regional‐scale increase likely driven by changes in methane. In austral summer, coincident changes in hydrogen cyanide suggest that decreases in local biomass burning can only partly explain the observed trend. In the absence of other explanations, we infer that the observed formaldehyde trend is likely driven by decreasing industrial emissions. In November, an observed increasing temperature trend is consistent with an earlier onset of biogenic emissions in the region, driving increased biogenic formaldehyde that counteracts the overall decrease.

Emissions from biomass burning have a large influence on atmospheric composition in the Southern Hemisphere where, relative to the Northern Hemisphere, slash and burn practices, pasture maintenance and accidental fires are more common and emissions from fossil fuels are much lower (Wai et al., 2014). Australia contributes

The Waroona fire burned 69 000 ha south of Perth in January 2016. There were two fatalities and 170 homes were lost. Two evening ember storms were reported and pyrocumulonimbus (pyroCb) cloud developed on consecutive days. The extreme fire behaviour did not reconcile with the near- surface conditions customarily used to assess fire danger. A case study of the fire (Peace et al. 2017) presented the hypothesis that the evening ember storms resulted from interactions between the above-surface wind fields, local topography and the fire plume. The coupled fire–atmosphere model ACCESS-Fire has been run in order to explore this hypothesis and other aspects of the fire activity, including the pyroCb development. ACCESS-Fire incorporates the numerical weather prediction model ACCESS (Australian Community Climate and Earth System Simulator, described by Puri et al. 2013) and a fire spread component. In these simulations, the Dry Eucalypt Forest Fire (Vesta) fire spread model is used. In this study we first show that the reconstruction of surface fire spread and simulated fire spread are a good match for the first day; second, we show that the model produces deep moist convection as an indicator of pyrocumulonimbus cloud and, third, we show the fire–atmosphere interactions surrounding the ember showers provided an environment conducive to the observed mass spotting. The simulation results demonstrate that ACCESS-Fire is a tool that may be used to further explore the complex processes and potential impacts surrounding pyroCb development and short-distance ember transport.