We demonstrate the transport and positioning of water droplets on macro-patterned lubricant-impregnated surfaces. The macro-patterning produces menisci features in the impregnating liquid layer which interact with a droplet via a capillary mechanism similar to the Cheerios effect. These interactions control the droplet motion and positioning on an otherwise completely slippery surface. We present experimental results using a V-shape channel geometry as a model system. The interaction between deformations on the lubricant layer induced by the droplet and the underlying V-shape geometry leads to both local and global equilibrium positions for the droplet within the channel. We present a mathematical model to quantify the transition from local equilibrium states to the global equilibrium state and show that the latter can be described on the basis of a force balance along the apparent contact line of the droplet. We highlight possible applications where lubricated macro-patterned surfaces can be used to control the motion and localisation of droplets.
We demonstrate the continuous translational invariance of the energy of a capillary surface in contact with reconfigurable solid boundaries. We present a theoretical approach to find the energyinvariant equilibria of spherical capillary surfaces in contact with solid boundaries of arbitrary shape and examine the implications of dynamic frictional forces upon a reconfiguration of the boundaries.Experimentally, we realise our ideas by manipulating the position of a droplet in a wedge geometry using lubricant-impregnated solid surfaces, which eliminate the contact-angle hysteresis and provide a test bed for quantifying dissipative losses out of equilibrium. Our experiments show that dissipative energy losses for an otherwise energy-invariant reconfiguration are relatively small, provided that the actuation timescale is longer than the typical relaxation timescale of the capillary surface. We discuss the wider applicability of our ideas as a pathway for liquid manipulation at no potential energy cost in low-pinning, low-friction situations.
We show how anisotropic, grooved features facilitate the trapping and directed transport of droplets on lubricated, liquid-shedding surfaces. Capillary action pins droplets to topographic surface features, enabling transport along the feature while inhibiting motion across (or detachment from) the feature. We demonstrate the robustness of this capillary-based mechanism for directed droplet transport on slippery surfaces by combining experiments on synthetic, lubricant-infused surfaces with observations on the natural trapping surface of a carnivorous pitcher plant.Controlling liquid navigation on synthetic surfaces promises to unlock significant potential in droplet-based technologies. Our observations also offer novel insight into the evolution of the Nepenthes pitcher plant, indicating that the 'pitfall' trapping mechanism is enhanced by the lubricant-infused, macroscopic grooves on the slippery peristome surface, which guide prey into the trap in a way that is more tightly controlled than previously considered.
The giant Amazonian waterlily (genus
Victoria
) produces the largest floating leaves in the plant kingdom. The leaves’ notable vasculature has inspired artists, engineers, and architects for centuries. Despite the aesthetic appeal and scale of this botanical enigma, little is known about the mechanics of these extraordinary leaves. For example, how do these leaves achieve gigantic proportions? We show that the geometric form of the leaf is structurally more efficient than those of other smaller species of waterlily. In particular, the spatially varying thickness and regular branching of the primary veins ensures the structural integrity necessary for extensive coverage of the water surface, enabling optimal light capture despite a relatively low leaf biomass. Leaf gigantism in waterlilies may have been driven by selection pressures favoring a large surface area at an economical material cost, for outcompeting other plants in fast-drying ephemeral pools.
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