Probing competent electrocatalysts for hydrogen evolution reaction (HER) of water splitting is one of the most hopeful approaches to confront the energy and environmental crisis. Herein, we highlight ultrathin N-doped MoC nanosheets (N-MoC NSs) in the role of greatly efficient platinum-free-based electrocatalysts for the HER. The transformation of crystal phase and structure between MoO nanosheets with a thickness of ∼1.1 nm and N-MoC NSs with a thickness of ∼1.0 nm is studied in detail. Structural analyses make clear that the surfaces of the N-MoC NSs are absolutely encompassed by apical Mo atoms, hence affording an ideal catalyst prototype to expose the role of Mo atoms for the duration of HER catalysis. Theoretical calculations demonstrate that the nanosheet structure, N doping, and particular crystalline phase of MoC produce more exposed Mo active sites, including Mo atoms on the C plane and doped N atoms. Through detailed electrochemical investigations, N-MoC NSs possess HER activity with an onset potential of -48.3 mV vs RHE, Tafel slope of 44.5 mV dec, and overpotential of 99 mV vs RHE at the cathodic current density of 10 mA cm with excellent long-term stability. Lastly, the calcination temperature and dicyandiamide amount can obviously affect the phase transformation and surface structure of molybdenum carbide, resulting in an adjustable HER activity. This synthesis mechanism will facilitate the understanding and optimization of Mo-based electrocatalysts in the energy conversion field.

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The removal of highly toxic, ultra-dilute contaminants of concern has been a primary challenge for clean water technologies. Chromium and arsenic are among the most prevalent heavy metal pollutants in urban and agricultural waters, with current separation processes having severe limitations due to lack of molecular selectivity. Here, we report redox-active metallopolymer electrodes for the selective electrochemical removal of chromium and arsenic. An uptake greater than 100 mg Cr/g adsorbent can be achieved electrochemically, with a 99% reversible working capacity, with the bound chromium ions released in the less harmful trivalent form. Furthermore, we study the metallopolymer response during electrochemical modulation by in situ transmission electron microscopy. The underlying mechanisms for molecular selectivity are investigated through electronic structure calculations, indicating a strong charge transfer to the heavy metal oxyanions. Finally, chromium and arsenic are remediated efficiently at concentrations as low as 100 ppb, in the presence of over 200-fold excess competing salts.

We report an atomic-scale characterization of ZrTe_{5} by using scanning tunneling microscopy. We observe a bulk band gap of ∼80  meV with topological edge states at the step edge and, thus, demonstrate that ZrTe_{5} is a two-dimensional topological insulator. We also find that an applied magnetic field induces an energetic splitting of the topological edge states, which can be attributed to a strong link between the topological edge states and bulk topology. The relatively large band gap makes ZrTe_{5} a potential candidate for future fundamental studies and device applications.