Ultrahigh sensitive piezoresistive sensors at small deformation are highly desired in many applications. Here, we propose a hierarchical contact design concept and implement it through a direct laser writing technique for fabricating layered carbon piezoresistive sensors with ultrahigh sensitivity. Sensors with unprecedented gauge factors (∼5000-10 000) at small deformation (ε < 0.1%) were successfully fabricated and demonstrated for their use in sensing both static and high-frequency (20-30 kHz) dynamic mechanical loads. A simple basic structure unit (BSU) contact network model was developed for understanding the importance of the BSU/BSU contact strength and network fractal dimension in dictating the piezoresistive sensitivity of the layered carbon piezoresistive sensors with designed hierarchical contact structures. The hierarchical contact design concept and the contact network model proposed in our work could open a general route for developing ultrasensitive piezoresistive sensors based on granular matter and composite materials.
The
carbonization process of the cheap and renewable biomass–sodium
lignosulfonate (NaLS) as a green carbon sources by an in-situ environmentally
friendly processing methoddirect laser writing carbonization
(DLWc)was investigated. With various characterization methods
the film formation conditions and laser processing parameters were
investigated for their effect on physical and chemical structures,
electrical, piezoresistive, and humidity response behaviors of the
carbon patterns. Besides its intrinsic piezoresistivity, the resistance
of the DLWc created carbon feature can also respond to moisture change.
With these dual characteristics, the carbon patterns were successfully
applied as piezoresistive and humidity sensors. A high gauge factor
of 120 was achieved for the piezoresistive sensor made of a square-shaped
carbon pattern. The work presented in this study indicates that the
application of DLWc to carbonize NaLS can create green carbon patterns
suitable for a variety of force and humidity related sensing applications.
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