Thiophenic compounds are the refractory organosulfur
compounds
remaining in the transportation fuels, and their removal from liquid
fuels has become increasingly important. In this work, adsorption
isotherms of thiophene (T), benzothiophene (BT), and dibenzothiophene
(DBT) in isooctane onto a metal–organic framework (Cu-BTC)
were measured for (293.15 to 313.15) K and equilibrium sulfur concentrations
up to 370 ppmw-S (ppmw of
sulfur). The adsorption capacity followed the order of BT < T <
DBT under the investigated sulfur concentrations and temperatures.
The adsorption isotherms of T and DBT are highly favorable. The isotherm
data were well-correlated using a multitemperature Langmuir model,
and three parameters were extracted for each thiophenic compound.
The multitemperature Langmuir model has predictive ability for the
adsorption of T, BT, and DBT within the sulfur concentration range
and the temperature range studied. The heat of adsorption (ΔH) of T, BT, and DBT is (−21.99, −14.23, and
−37.34) kJ·mol–1, respectively. The
order of ΔH is in agreement with the adsorption
affinities.
This study was designed to detect characteristic compounds and evaluate the free radical scavenging capacity of the bamboo leaves extract and bamboo shavings extract (BSE). The antioxidant capacity of bamboo leaf n-butanol fraction (AOB) exhibited the highest total phenolic content (49.93%), total flavonoids content (24.11%), and characteristic flavonoids and phenolic acids, such as chlorogenic acid, caffeic acid, ferulic acid, p-coumaric acid, orientin, homoorientin, vitexin, and isovitexin. Available data obtained with in vitro models suggested that AOB had higher free radical scavenging capacity with IC(50) values of 1.04, 4.48, 5.37, and 1.12 μg/mL on DPPH(•), O(2)(•-), (•)OH, and H(2)O(2), respectively, than the other two extracts, bamboo leaf water extract and BSE. The results indicated that the extracts from different parts of the bamboo possess excellent antioxidant activity, which can be used potentially as a readily accessible and valuable bioactive source of natural antioxidants.
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