A new cationic gemini surfactant (C25‐6‐C25), which had a special structure consisting of ultra‐long hydrophobic chains and amide groups, was synthesized using a main feedstock source obtained from rapeseed for thickening purposes. The 12 mmol L−1 C25‐6‐C25 fluid containing 0.19 mol L−1 potassium chloride (KCl) exhibited highly elastic properties at the angular frequency of 0.04–10 rad s−1. Its viscosity could be maintained at 55 mPa s for 1.5 h under a shear rate of 170 s−1 at 110 °C and it also showed a good proppant‐suspending property. C25‐6‐C25/KCl fluid exhibited high viscoelasticity and good performance, which were attributed to intermolecular forces, hydrogen bonding, and the shielding effect of electrostatic repulsion by KCl. Thus, C25‐6‐C25 is a very promising candidate for fracturing. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 44602.

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The rational design and in-depth understanding of the structure–activity relationship (SAR) of hydrogen and oxygen evolution reaction (HER and OER) bifunctional electrocatalysts are vital to decreasing the energy consumption of hydrogen production by electrochemical water splitting. Herein, we report an inducing electron delocalization method where Fe single atoms as inducers are used to regulate the electron structure of Au nanoclusters by the M–N x –C substrate to acquire satisfactory intrinsic HER activity. Meanwhile, Fe single atoms also serve as efficient OER active sites to construct bifunctional electrocatalysts. On account of the strong synergistic effect between Au nanoclusters and Fe single atoms, the hybrid catalyst Au-Fe1NC/NF performs an outstanding alkaline HER and OER activity. Only 35.6 mV, 246 mV, and 1.52 V are needed to reach 10 mA cm–2 for alkaline HER, OER, and two-electrode electrolytic cells, respectively. In addition, the bifunctional electrocatalysts also display excellent electrochemical stability. DFT calculations demonstrate that the strong synergistic effect can enhance the O–H bond activation ability of Au nanoclusters and upshift the d-band center of the Fe single atom to promote alkaline electrocatalytic water splitting. The strong synergistic effect is proven to arise from the electron delocalization of Au nanoclusters triggered by Fe single atoms.