Two-dimensional (2D) transition metal dichalcogenides (TMDs) have stimulated the modern technology due to their unique and tunable electronic, optical, and chemical properties. Therefore, it is very important to study the control parameters for material preparation to achieve high quality thin films for modern electronics, as the performance of TMDs-based device largely depends on their layer number, grain size, orientation, and morphology. Among the synthesis methods, chemical vapor deposition (CVD) is an excellent technique, vastly used to grow controlled layer of 2D materials in recent years. In this review, we discuss the different growth routes and mechanisms to synthesize high quality large size TMDs using CVD method. We highlight the recent advances in the controlled growth of mono- and few-layer TMDs materials by varying different growth parameters. Finally, different strategies to control the grain size, boundaries, orientation, morphology and their application for various field of are also thoroughly discussed.
The anisotropy of GaN(11-20) makes it possible to fabricate polarized ultraviolet (UV) photodetectors (PDs) for applications in fields such as remote sensing and airborne astronomical navigation. The defect density has a significant effect on the performance of GaN(11-20)-based UV PDs. However, the mechanism through which different defects and their densities affect the performance of these devices is unclear. Therefore, in this work, we investigated the mechanisms of the screw or mixed dislocation, edge dislocation, and basal stacking fault (BSF) densities affecting the dark current, responsivity, and response time of GaN (11-20)-based PDs, respectively. We observed that the screw or mixed dislocation increased the dark current mainly through reducing the Schottky barrier height and forming leakage current, whereas the edge dislocation and BSF decreased the responsivity by reducing the electron mobility. Furthermore, all the three types of defects increased the response time through forming traps to recombine the holes with electrons and thus delaying the escape of carriers. These results are highly significant for developing nonpolar GaN-based UV PDs.
With the increasing demand for wearable and implantable electronics, structured sensors with exceptional performance in sensitivity, stretchability, biocompatibility, and adhesion to the biological surfaces have become essential.
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