Developing efficient and stable oxygen evolution reaction (OER) electrocatalysts via doping strategy has well-documented for electrochemical water splitting. Herein, a homogeneous structure (denoted as Co/Ce-Ni 3 S 2 /NF) composed of Co and Ce dual doped Ni 3 S 2 nanosheets on nickel foam was synthesized by a facile one-step hydrothermal method. Co and Ce dopants are distributed inside the host sulfide, thereby raising the active sites and the electrical conductivity. Besides, the CeO x nanoparticles generated by part of the Ce dopants as a cocatalyst further improve the catalytic activity by adding defective sites and enhancing the electron transfer. As a consequence, the obtained Co/Ce-Ni 3 S 2 /NF electrode exhibits better electrocatalytic activity than single Co or Ce doped Ni 3 S 2 and pure Ni 3 S 2 , with low overpotential (286 mV) at 20 mA•cm −2 , a small Tafel slope and excellent long-term durability in strong alkaline solution. These results presented here not only offer a novel platform for designing transition metal and lanthanide dual-doped catalysts, but also supply some guidelines for constructing catalysts in other catalytic applications.

CoP nanosheets decorated by in-situ CeOx nanoparticles were designed through a novel two-step solvothermal-phosphating strategy, which act as an electrode exhibit excellent electrocatalytic performance toward OER in alkaline condition.

Solid solution-oxide heterostructures combine the advantages of solid solution and heterojunction materials to improve electronic structure and optical properties by metal doping, and enhance charge separation and transfer in semiconductor photocatalysts by creating a built-in electric field. Nevertheless, the effective design and synthesis of these materials remains a significant challenge. Here, we develop a generally applicable strategy that leverages the transformable properties of metal-organic frameworks (MOFs) to prepare solid solution-oxide heterojunctions with controllable structural and chemical compositions. The process consists of three main steps. First, MOFs with different topological structures and metal centers are transformed, accompanied by pre-nucleation of a metal oxide. Second, solid solution is prepared through calcination of the transformed MOFs. Finally, a heterojunction is formed by combining solid solution with another metal oxide group through endogenous overflow. DFT calculations and study on carrier dynamics show that the structure of the material effectively prevents electrons from returning to the bulk phase, exhibiting superior photocatalytic reduction performance of CO 2 . This study is expected to promote the controllable synthesis and research of MOF-derived heterojunctions.

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