Polymer network liquid crystal (PNLC) was one of the most potential liquid crystal for submillisecond response phase modulation, which was possible to be applied in submillisecond response phase only spatial light modulator. But until now the light scattering when liquid crystal director was reoriented by external electric field limited its phase modulation application. Dynamic response of phase change when high voltage was applied was also not elucidated. The mechanism that determines the light scattering was studied by analyzing the polymer network morphology by SEM method. Samples were prepared by varying the polymerization temperature, UV curing intensity and polymerization time. The morphology effect on the dynamic response of phase change was studied, in which high voltage was usually applied and electro-striction effect was often induced. The experimental results indicate that the polymer network morphology was mainly characterized by cross linked single fibrils, cross linked fibril bundles or even both. Although the formation of fibril bundle usually induced large light scattering, such a polymer network could endure higher voltage. In contrast, although the formation of cross linked single fibrils induced small light scattering, such a polymer network cannot endure higher voltage. There is a tradeoff between the light scattering and high voltage endurance. The electro-optical properties such as threshold voltage and response time were taken to verify our conclusion. For future application, the monomer molecular structure, the liquid crystal solvent and the polymerization conditions should be optimized to generate optimal polymer network morphology.
Higher spatial resolution indicates sharper recognition ability in applications. To improve the spatial resolution of volume Bragg grating spectral imagers, quantitative wave vector theory is used to elucidate the formation mechanism of diffraction blur, and the corresponding optimal design approaches are put forward. The simulation results show that the main factors for the spectral image blur are the chromatic blur and diffraction aberration, while the central wavelength deviation further deteriorates these. To deal with these factors, one must optimize the grating period, thickness, slant angle, and refractive index, as well as compress the divergence angle of the incident beam. After optimization under the guidance of the newly defined integrated merit functions, the experimental results show that the optimized smeared point-spread function is reduced by about an order of magnitude. The horizontal spatial resolution of the recorded two-dimensional monochromatic images is improved to 14.3 lines/mm under diffuse reflection illumination.
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