Purification of ethylene (C2H4), the largest-volume product of the chemical industry, currently involves energy-intensive processes such as chemisorption (CO2 removal), catalytic hydrogenation (C2H2 conversion), and cryogenic distillation (C2H6 separation). Although advanced physisorbent or membrane separation could lower the energy input, one-step removal of multiple impurities, especially trace impurities, has not been feasible. We introduce a synergistic sorbent separation method for the one-step production of polymer-grade C2H4 from ternary (C2H2/C2H6/C2H4) or quaternary (CO2/C2H2/C2H6/C2H4) gas mixtures with a series of physisorbents in a packed-bed geometry. We synthesized ultraselective microporous metal-organic materials that were readily regenerated, including one that was selective for C2H6 over CO2, C2H2, and C2H4.
Chronic bacterial-infected wound healing/skin regeneration remains a challenge due to drug resistance and the poor quality of wound repair. The ideal strategy is combating bacterial infection, while facilitating satisfactory wound healing. However, the reported strategy hardly achieves these two goals simultaneously without the help of antibiotics or bioactive molecules. In this work, a two-dimensional (2D) Ti 3 C 2 T x MXene with excellent conductivity, biocompatibility, and antibacterial ability was applied in developing multifunctional scaffolds (HPEM) for methicillin-resistant Staphylococcus aureus (MRSA)-infected wound healing. HPEM scaffolds were fabricated by the reaction between the poly(glycerol-ethylenimine), Ti 3 C 2 T x MXene@polydopamine (MXene@PDA) nanosheets, and oxidized hyaluronic acid (HCHO). HPEM scaffolds presented multifunctional properties containing selfhealing behavior, electrical conductivity, tissue-adhesive feature, antibacterial activity especially for MRSA resistant to many commonly used antibiotics (antibacterial efficiency was 99.03%), and rapid hemostatic capability. HPEM scaffolds enhanced the proliferation of normal skin cells with negligible toxicity. Additionally, HPEM scaffolds obviously accelerated the MRSAinfected wound healing (wound closure ratio was 96.31%) by efficient anti-inflammation effects, promoting cell proliferation, and the angiogenic process, stimulating granulation tissue formation, collagen deposition, vascular endothelial differentiation, and angiogenesis. This study indicates the important role of multifunctional 2D MXene@PDA nanosheets in infected wound healing. HPEM scaffolds with multifunctional properties provide a potential strategy for MRSA-infected wound healing/skin regeneration.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.