The Cu-Cr and Cu-Cr-Ti alloy plates were prepared by vacuum melting and plastic deformation. The effect of slight Ti element on microstructure and mechanical properties of Cu-Cr alloy was discussed. The result shows that Cr particles with spherical shape precipitated from Cu matrix after aging. Plenty Ti atoms dissolved in the vicinity of Cr particles and there were still parts of solid solution Ti atoms in other regions. Improvements in peak hardness and softening resistance were achieved with the addition of Ti element in Cu-Cr alloy. The addition of 0.1 wt.% Ti element makes Cu-Cr alloy possess tensile strength of 565 MPa and hardness of 185.9 HV after aging at 450 °C for 120 min, which can be attributed to multiple strengthening mechanisms, i.e. work hardening, solid solution strengthening and precipitation strengthening.
Cu-Ag-Zr alloy is a newly developed copper alloy material with an excellent combination of high mechanical strength and high electrical conductivity. Magnetic field was used in the solidification of Cu-Ag-Zr alloy. The results showed that with the application of magnetic field, formerly coarse columnar grain turned into homogeneous equiaxed grain. After aging, the precipitate of Zr had an increment and became more refined due to the reduction of segregation. The tensile strength and microhardness of Cu-0.1Ag-0.3Zr alloy under magnetic field of 15 mT increased by 17% and 10%, respectively. The electrical conductivity, with a slight decrease, was still as high as 92.4 %IACS.
The effect of different alloying elements on corrosion behavior of copper alloys was investigated using electrochemical corrosion and salt spray corrosion test in NaCl solution. Cu-Ag has the most stable corrosion current in the potentiostatic scanning test, exhibiting a better corrosion resistant performance. It can be analyzed from corrosion surface morphologies that Cu-Ag presents exfoliation corrosion mechanism while Cu-Sn shows crevice corrosion mechanism. Cu-Mg has a complex corrosion process caused by multiple corrosion mechanism. In the salt spray corrosion test, the corrosion degree of Cu-Ag is lighter than those of Cu-Sn and Cu-Mg after 24h test. Therefore, the Cu-Ag alloy exhibits the best corrosion resistance in chloride solution.
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