Abstract:The purpose of the biomass torrefaction and pelletizing processes is to increase its energy properties, be environmentally friendly, decrease shipping costs, and make handling easier. The objective of the present work is to evaluate the density, internal density variation by X-ray densitometry, moisture content, water absorption, and compression force of torrefied biomass pellets of five wood species (Cupressus lusitanica, Dipterix panamensis, Gmelina arborea, Tectona grandis, and Vochysia ferruginea) under three torrefaction temperature conditions (light, middle, and severe) and three torrefaction times (8, 10, and 12 min). The results showed that the bulk density of the pellets was 0.90-1.30 g/cm 3 . The density variation of the pellets was higher with torrefaction at 250 • C. The moisture content decreased with increasing torrefaction temperature from 3% to 1%. Water absorption was lower in the pellets torrefied at 250 • C. The compression force was lower in the pellets torrefied at 250 • C with approximate loads of 700 N. Based on the above results, it was concluded that pellets made with biomass torrefied at 200 • C have better energy properties and evaluated properties. According to these results, pellets fabricated with the torrefied biomass of tropical species can be used in stove, gas, and hydrogen production because the pellet presents adequate characteristics.

We evaluated the thermogravimetric and devolatilization rates of hemicellulose and cellulose, and the calorimetric behavior of the torrefied biomass, of five tropical woody species (Cupressus lusitanica, Dipteryx panamensis, Gmelina arborea, Tectona grandis and Vochysia ferruginea), at three temperatures (T T ) and three torrefaction times (t T ) using a thermogravimetric analyzer. Through a multivariate analysis of principal components (MAPC), the most appropriate torrefaction conditions for the different types of woody biomass were identified. The thermogravimetric analysis-derivative thermogravimetry (TGA-DTG) analysis showed that a higher percentage of the hemicellulose component of the biomass degrades, followed by cellulose, so that the hemicellulose energy of activation (Ea) was less than that of cellulose. With an increase in T T and t T , the Ea for hemicellulose decreased but increased for cellulose. The calorimetric analyses showed that hemicellulose is the least stable component in the torrefied biomass under severe torrefaction conditions, and cellulose is more thermally stable in torrefied biomass. From the MAPC results, the best torrefaction conditions for calorimetric analyses were at 200 and 225 • C after 8, 10, and 12 min, for light and middle torrefaction, respectively, for the five woody species.

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This work aimed to evaluate the effect of the precipitation of CaCO3 via subsequential in-situ mineral formation based on a solution-exchange process of two solution-exchange cycles via impregnation with CaCl2 in ethanol and NaHCO3 in water. The effects were investigated in terms of the structure of the wood and the thermal, physical, mechanical, and decay resistance properties of nine species commonly used in commercial reforestation in Costa Rica. The thermogravimetric analysis results showed that the woods with the highest formation of CaCO3 showed a more pronounced signal at 200 °C in relation to untreated/wood; therefore, they were more thermostable. The fire-retardancy test showed that flame time in CaCO3/wood composites was longer than for untreated/wood in half of the species tested, presenting a positive effect of mineralization. Wood density, decay resistance, modulus of rupture (MOR), modulus of elasticity (MOE) in flexion, and MOR in compression were slightly affected by mineralization. Water absorption increased, but it had no negative effect on the dimensional stability. In general, mineralization can be a chemical treatment to increase the dimensional stability and fire resistance of hardwood species without modifying the wood’s physical and mechanical properties.

T orrefaction and pelletizing were studied in the generation of energy from lignocellulosic residues to increase the energy properties of the biomass. The aim of this study was torrefied sawdust from Gmelina arborea and Dipteryx panamensis at 200 °C in three time period: 0, 15 and 20 minutes. Then with the biomass, pellets of 6 mm diameter were manufactured and their physical properties, calorific value, density and compression force were evaluated. Both species had similar physical characteristics according to the average diameter (0.50 mm), length (21.50 mm), and water absorption rate (6.00 %). The calorific value increased from 9,749 kJ·kg -1 in un-terrified biomass to 18,126 kJ·kg -1 with torrefied biomass. The pellets from D. panamesis had greater density and compression force compared to G. arborea biomass. Based on the results, pellet compression force decreases as the torrefaction time increases. There is positive correlation between bulk density of pellets and compression force. The D. panamensis species has better torrefaction behavior and pelletizing than the wood of G. arborea. ResumenL a torrefacción y peletización se han estudiado en la generación de calor a partir de residuos lignocelulósicos, para incrementar las propiedades energéticas del material. El objetivo del presente trabajo fue torrefaccionar aserrín de Gmelina arborea y Dipteryx panamensis a 200 °C en tres tiempos: 0, 15 y 20 minutos. Con las biomasas obtenidas se fabricaron pellets de 6 mm de diámetro y se evaluaron sus propiedades físicas, el poder calórico, la densidad y la propiedad mecánica de resistencia a la compresión. Ambas especies presentaron características físicas similares con respecto al diámetro (0.50 mm), longitud (21.50 mm) y porcentaje de absorción de agua (6.00 %). El poder calórico aumentó de 9,749 kJ·kg -1 en la biomasa sin torrefaccionar a 18,126 kJ·kg -1 en la biomasa torrefaccionada. Los pellets de D. panamesis presentaron mayor densidad y resistencia a la compresión que los de G. arborea. Con base en los resultados, la resistencia a la compresión del pellet disminuye cuando el tiempo de torrefacción aumenta. Existe correlación positiva entre la densidad de los pellets y la resistencia a la compresión. La especie D. panamensis presenta mejor comportamiento a la torrefacción y peletización que la madera de G. arborea.