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constant) of a material emerged as an elegant method of estimating water content in porous materials. For the Substantial advances in the measurement of water content and first time the same physical property (permittivity) could bulk soil electrical conductivity (EC) using time domain reflectometry be measured for a range of scales and used to estimate (TDR) have been made in the last two decades. The key to TDR's success is its ability to accurately measure the permittivity of a material water content. Electromagnetic methods, whether TDR and the fact that there is a good relationship between the permittivity (localized measurement), ground penetrating radar of a material and its water content. A further advantage is the ability (two-dimensional profile), or active microwave remote to estimate water content and measure bulk soil EC simultaneously sensing (land surface), all estimate water content based using TDR. The aim of this review is to summarize and examine on the permittivity of the target medium. A further advances that have been made in terms of measuring permittivity and advance was the development of analysis methods using bulk EC. The review examines issues such as the effective frequency TDR. Time domain reflectometry was adapted to estiof the TDR measurement and waveform analysis in dispersive dielecmate both soil water content (Hoekstra and Delaney, trics. The growing importance of both waveform simulation and in-1974; Topp et al., 1980) and soil bulk EC simultaneously verse analysis of waveforms is highlighted. Such methods hold great (Dalton et al., 1984). In spite of decades of research, potential for obtaining far more information from TDR waveform analysis. Probe design is considered in some detail and practical guid-we are only beginning to efficiently utilize electrical ance is given for probe construction. The importance of TDR measuretechnology that ranges from satellite and airborne radar ment sampling volume is considered and the relative energy storage to ground penetrating radar and localized sensors such density is modeled for a range of probe designs. Tables are provided as TDR and impedance probes. that compare some of the different aspects of commercial TDR equip-The underlying success of these techniques can be ment, and the units are discussed in terms of their performance and considered in two parts, the first of which is the equiptheir advantages and disadvantages. It is hoped that the review will ment's ability to accurately measure the bulk dielectric provide an informative guide to the more technical aspects of permitpermittivity and EC of a material. The second is the close tivity and EC measurement using TDR for the novice and expert alike.relationship between the measured permittivity and the volumetric water content, or the ionic concentration and the bulk EC of the material. This review concentrates

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Abstract. Near-surface measurements of soil water content (0) using time domain reflectometry (TDR) may exhibit anomalous behavior in the presence of diurnal temperature (T) fluctuations. Experimental results obtained in a companion paper led to the hypothesis that the observed bulk dielectric permittivity (eb) is determined by an interplay between two competing phenomena: (1) the reduction in the dielectric permittivity of bulk water with increased T; and (2) the increase in TDR-measured •:b with increased T due to release of bound water. In this study we develop a physically based model for the temperature dependency of TDR-measured soil bulk dielectric permittivity and propose practical correction factors. The model considers the modified properties of water near solid surfaces to define a layer of rotationally hindered water (within the TDR frequency bandwidth) having a temperature dependent thickness. Changes in measured eb(T) are thus attributed to variations in the thickness of the rotationally hindered layer which has a lower dielectric permittivity than free water and hence is less "visible" to travel-time-based TDR waveform analyses. The model is sensitive to the soil specific surface area and the water content, both of which determine the ratio of bound to bulk soil water. Comparisons with experimental data covering a wide range of soils, water contents, and temperatures showed good agreement. Further studies are needed to evaluate some of the model's critical parameters such as the cutoff frequency below which water is considered bound. A temperature correction approximation is based on analytical expressions for TDR-measured bulk dielectric permitivity and requires estimates of soil specific surface area and bulk density, which may be estimated from soil texture. The thermodielectric sensitivity of TDR-measured bulk dielectric permittivity and water content may serve as a basis for estimating soil specific surface area.

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