One of the consequences of industrial food production activities is the generation of high volumes of waste, whose disposal can be problematic, since it occupies large spaces, and when poorly managed can pose environmental and health risks for the population. The rice industry is an important activity and generates large quantities of waste. The main solid wastes generated in the rice production cycle include straw, husk, ash, bran and broken rice. As such, the aim of this article is to present a review of this cycle, the waste generated and the identification of opportunities to use them. Owing to impacts that can be minimised with the application of rice husk ash as a by-product, this work is focused on the recycling of the main wastes. In order to achieve that, we performed theoretical research about the rice production cycle and its wastes. The findings point to the existence of an environmentally suitable use for all wastes from the rice production cycle. As rice, bran and broken rice have their main use in the food industry, the other wastes are highly studied in order to find solutions instead of landfilling. Straw can be used for burning or animal feeding. The husk can be used for poultry farming, composting or burning. In the case of burning, it has been used as biomass to power reactors to generate thermal or electrical energy. This process generates rice husk ash, which shows potential to be used as a by-product in many different applications, but not yet consolidated.
The aromatic petroleum hydrocarbons (benzene, toluene, ethylbenzene and xylenes) are highly volatile and toxic to human health and the environment. Adsorption is a physical-chemical process widely used in effluent treatment in which a material called adsorbate has the capacity to retain components dispersed in an aqueous medium on its surface. Studies of waste recovery demonstrate potentialities and more noble uses than the final disposal. In this sense, the ashes generated from the combustion of rice husk can be used as a by-product with various applications; in the case of this work, as adsorbent material, due to its amorphism and its high surface area. This study aimed to evaluate the adsorption of the aromatic components of a petrochemical effluent (formation water) with the use of two types of rice husk ash generated from two different grate combustion processes in a filtration system under positive pressure. The ashes were segregated and characterized according to their physical, chemical, mineralogical, and microstructural properties. The adsorption procedure by percolation consisted of 1L of petrochemical effluent for 45 g of adsorbent material. The samples of raw effluent were analyzed by gas chromatography. The results proved that the percentage of removal of BTEX composts in the segregated ash I did not potentialize the effect of the adsorption, being higher in the raw ash, with values of 90.2; 94.9; 83.3 and 100 %, while in ash II the effect of the segregation influenced the adsorption process only for the benzene and toluene, with removal values that went from 55.08 to 69.14 % and 69.23 to 75 %, respectively, in both of the ashes studied. The results obtained were inferior to those recommended by the legislation. Thus, the different combustion temperatures of the husk influenced in the characteristics, adsorption capacity, and BTEX removal efficiency by the adsorbate. Therefore, the positive filtration system can be used as a final polishing step in the treatment of petrochemical effluents, replacing conventional systems that use activated carbon.
The estimate rice productivity in Brazil for the 2008/2009 season, is 12,149.35 thousand tons of grains, being Rio Grande do Sul (RS) state responsible for 61.34% of national production. The rice shell is usually burned for energy production, generating rice shell ash (CCA) as solid residue. CCA represents an average of 4% of the grain mass. In this way, RS state presents an estimated generation of 298.1 thousand tons of CCA in this period. Attempts to reuse this waste are constantly facing difficulties due to inherent CCA properties. This work aims to perform sorption bench tests to verify the possibility of using CCA to treat the effluent of the parboiled process. Tests efficiencies were expressed in terms of organic matter and turbidity removal. The use of a solid residue of the end of the process to treat the effluent of the very process is a strategy to minimize costs for waste management and contribute to the environment in a sustainable way. The sorption efficiency of CCA as an alternative sorbent material reached 78% of organic matter removal and 99% of turbidity removal.
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