ITO-free polymer solar cells with efficiencies as high as 6.6% and 5.8% are fabricated on glass and polyethylene naphthalate (PEN) by using TeO(2) to enhance the in-coupling of light in an Ag-Ag microcavity. These cells exhibit higher performance, selective microcavity resonance as a function of the thickness of TeO(2) , and better bending stability than flexible devices made with ITO.
Organic solar cells often show inefficient light harvesting due to a short absorption path length limited by the low charge mobility of organic semiconductors. We demonstrate a flexible organic solar cell in a microcavity configuration using a TeO2/Ag semitransparent electrode to confine the optical field within the device with significant performance improvements and reaching a power conversion efficiency of 8.56%.
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