Memristors have attracted significant interest in recent years because of their role as a missing electronic component and unique functionality that has not previously existed. Since the first discoveries of the existence of memristive materials, various different fabrication processes for memristors have been presented. Here, a simple additive fabrication process is demonstrated where memristors were deposited on a polymer substrate by conventional inkjet printing. The memristor structure was printed on a 125 μm thick polyethylene terephthalate (PET) substrate by sandwiching a thin layer of TiO x between two silver nanoparticle ink electrodes. Current-voltage (IV) characterization measurements were performed and they showed clear memristive behavior when voltage pulse amplitude varied between −1.5 V and 1.5 V. The corresponding resistance change is approximately between 150 Ω and 75 kΩ. In order to demonstrate the switching scheme in practical application, printed memristors and a printed voltage doubler were connected with a piezoelectric element. The element was subjected to impact-type excitation thus producing an electric charge that was able to switch the memristor between high and low resistive states. These results pave the way for an exploitation of cost-efficient, self-sufficient, all-printable memory elements for wide utilization in future electronics applications.
We report a flexible energy harvesting circuit fabricated by roll-to-roll compatible, solution-processable methods. The circuit incorporates a supercapacitor fabricated from a viscous carbon nanotube dispersion, printed Schottky diodes, and a piezoelectric element. Used low-temperature materials enabled component integration on poly(ethylene terephthalate) substrate. The supercapacitor was built with a paper separator and an aqueous NaCl electrolyte. Together with carbon-based electrodes, these materials translated into a disposable and environmentally safe electronic device. The energy harvested from mechanical movement was used to drive a commercial electrochromic display.
We report the fabrication and characterization of supercapacitors prepared on a flexible substrate using a printable, high-viscosity carbon nanotube (CNT) ink. The CNT-hemicellulose composite ink was prepared using ultrasonication and applied on the substrate with a doctor blade. Aqueous sodium chloride was used as electrolyte. The capacitance of the supercapacitors was 16 mF for a device size of 2 cm2. The measurements were carried out in accordance to an international standard for electric double layer capacitors.
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