Diesel particulate filter is an effective device to reduce diesel particulate emission. The particles in diesel particulate filter are usually affected by the aging of high-temperature exhaust gas before the regeneration process. In order to investigate the effect of aging conditions on the soot oxidation process, the effect of aging temperature and aging time on the oxidation process of carbon black (Printex-U, PU) and the PU/catalyst/ash mixture are studied by thermogravimetric analysis. The aging PU particles have lower starting temperature, peaking temperature, ending temperature, and activation energy. Compared with the particles without aging, the PU particles with a 400 °C aging temperature and 20 h aging time are able to reduce the activation energy from 191.2 to 158 kJ/mol. Low aging temperatures (200–300 °C) and the catalyst have a certain synergistic effect on the improvement of PU oxidation activity. The PU/CeO2 mixture with a 300 °C aging temperature and 20 h aging time decreases the activation energy from 178.4 to the lowest 113.6 kJ/mol. The addition of CaSO4 in PU particles cannot stop the improvement of its oxidation activity by aging, but it reduces the effect of aging. This work is helpful to reveal the mechanism of aging on PU and the PU/catalyst/ash mixture in air environment.

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The application of hydrogen fuel in ORP engines makes the engine power density much higher than that of a reciprocating engine. This paper investigated the impacts of combustion characteristics, energy loss, and NOx emissions of a hydrogen-fuelled ORP engine by ignition timing over various equivalence ratios using a simulation approach based on FLUENT code without considering experiments. The simulations were conducted under the equivalence ratio of 0.5~0.9 and ignition timing of −20.8~8.3 °CA before top dead centre (TDC). The engine was operated under 1000 RPM and wide-open throttle condition which was around the maximum engine torque. The results indicated that significant early ignition of the ORP engine restrained the flame development in combustion chambers due to the special relative positions of ignition systems to combustion chambers. In-cylinder pressure evolutions were insensitive to early ignition. The start of combustion was the earliest over the ignition timing of −17.3 °CA for individual equivalence ratios; the correlations of the combustion durations and equivalence ratios were dependent on the ignition timing. Combustion durations were less sensitive to equivalence ratios in the ignition timing range of −14.2~−11.1 °CA before TDC. The minimum and maximum heat release rates were 15 J·(°CA)−1 and 22 J·(°CA)−1 over the equivalence ratios of 0.5 and 0.9, respectively. Indicated thermal efficiency was higher than 41% for early ignition scenarios, and it was significantly affected by late ignition. Energy loss by cylinder walls and exhaust was in the range of 10%~16% and 42%~58% of the total fuel energy, respectively. The impacts of equivalence ratios on NOx emission factors were affected by ignition timing.

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