No abstract

No abstract

No abstract

The glass-ceramic mainly containing fluorophlogopite is one of widely used dental ceramics. In the K2O-CaO-MgO-Al2O3-SiO2-F system, a new-type glass-ceramic containing fluorophlogopite Ca-mica has been synthesized. Its crystalline was studied by XRD and EDS. The fluorophlogopite whose formula postulated K(1 - X )Ca( X/2)Mg(3)AlSi(3)O(10)F(2) was its main crystalline. The microstructure of the glass-ceramic displayed typical machinable microstructure with lath like crystals isolated and interlocking with different aspect ratio. The material also showed better bending strength (228.11 +/- 7.55 MPa). It took less than 12 minutes to fabricate a whole crown by dental CAD/CAM system with the glass-ceramic.

Metal halide perovskites (MHPs) have attracted attention because of their high optoelectronic performance that is fundamentally rooted in the unusual properties of MHP defects. By developing an ab initio-based machine-learning force field, we sample the structural dynamics of MHPs on a nanosecond time scale and show that halide vacancies create midgap trap states in the MHP bulk but not on a surface. Deep traps result from Pb−Pb dimers that can form across the vacancy in only the bulk. The required shortening of the Pb−Pb distance by nearly 3 Å is facilitated by either charge trapping or 50 ps thermal fluctuations. The large-scale structural deformations are possible because MHPs are soft. Halide vacancies on the MHP surface create no deep traps but separate electrons from holes, keeping the charges mobile. This is particularly favorable for MHP quantum dots, which do not require sophisticated surface passivation to emit light and blink less than quantum dots formed from traditional inorganic semiconductors.