Industrialization and the growing consumption of medicines leads to global aquatic contamination. One of the antibiotics widely used against bacterial infections in both human and veterinary medicine is tetracycline. Despite its positive antibiotic action, tetracycline is resistant against degradation, and therefore it accumulates in the environment, including the aquatic environment, creating great health hazards, possibly stimulating antibiotic resistance of pathogenic organisms. In this research, aqueous suspensions of semiconductor nanoparticles CdS were used for photocatalytic activity studies in the presence of methylene blue as a model compound, and finally, in the presence of tetracycline, a broad-spectrum antibiotic widely used against bacterial infections, as well as a live-stock food additive. The mechanism and kinetic rate constants of photocatalytic degradation processes of methylene blue and tetracycline were described in correlation with the energy diagram of CdS nanoparticles.

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Comparative photoelectrochemical studies of cadmium sulfide (CdS) nanoparticles with either hydrophilic or hydrophobic surface properties are presented. Oleylamine organic shells provided CdS nanoparticles with hydrophobic behavior, affecting the photoelectrochemical properties of such nanostructured semiconductor. Hydrophilic CdS nanoparticles were drop-cast on the electrode, whereas the hydrophobic ones were transferred in a controlled manner with Langmuir-Blodgett technique. The substantial hindrance of photopotential and photocurrent was observed for L-B CdS films as compared to the hydrophilic, uncoated nanoparticles that were drop-cast directly on the electrode surface. The electron lifetime in both hydrophilic and hydrophobic nanocrystalline CdS was determined, revealing longer carrier lifetime for oleylamine coated CdS nanoparticles, ascribed to the trapping of charge at the interface of the organic shell/CdS nanoparticle and to the dominant influence of the resistance of the organic shell against the flux of charges. The “on” transients of the photocurrent responses, observed only for the oleylamine-coated nanoparticles, were resolved, yielding the potential-dependent rate constants of the redox processes occurring at the interface.

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