This article considers an effective way of processing natural and technogenic magnesium-containing materials, which will release magnesium oxide and magnesium sulphate for the production of magnesian cement. Using this method, pure magnesium oxide, magnesium sulphate and magnesium sulfate have been obtained, the study considers the properties of magnesian cement with differeng magnesium oxide production conditions. Keywords: non-conventional magnesium containing raw materials, technogenic materials, magnesian cement, hydrochemical processing, ammonium hydrosulfate

The results of a comprehensive study of the material composition and microstructure of 20 skull samples taken after blowing out blast furnace № 6 of EVRAZ NTMK JSC are presented. More than 30 minerals and metal phases of different chemical classes were diagnosed in the samples of the skull. Unlike the skull of blast furnaces of other metallurgical plants (NLMK, ZSMK), the skull of NTMK blast furnaces has an abnormally high content of titanium, zinc, vanadium compounds, as well as heavy non-ferrous metals and sulfur. On the basis of a detailed petrographic analysis, 5 structural and genetic types (varieties in composition and origin) of the garnice were identified. The varieties of the garnish contain a large amount of grenal, which is dominated by refractory compounds of titanium and vanadium carbonitrides of the general formula (Ti, V) (C, N).

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