Plastic products are made from the essential polymer mixed with a complex blend of substances including catalyst remnants, polymerization solvents, and a wide range of other additives deliberately added to enhance the desirable characteristics of the final product. Additives include bisphenols, phthalates, flame retardants, and further emerging and legacy contaminants. With a few exceptions, additives are not chemically bound to the polymer, and potentially migrate within the material reaching its surface, then possibly leach out to the environment. Leachates are mixtures of additives, some of which belong to the list of emerging contaminants, i.e. substances that show the potential to pose risks to the environment and human health, while are not yet regulated. The review discusses the state of the art and gaps concerning the hidden threat of plastic leachates. The focus is on reports addressing the biological impacts of plastic leachates as a whole mixture. Degradation of plastics, including the weathering-driven fragmentation, and the release of additives, are analysed together with the techniques currently employed for chemically screening leachates. Because marine plastic litter is a major concern, the review mainly focuses on the effects of plastic leachates on marine flora and fauna. Moreover, it also addresses impacts on freshwater organisms. Finally, research needs and perspectives are examined, to promote better focused investigations, that may support developing different plastic materials and new regulations.
Groundwater is one of the most important natural resources in the northern coastal belt of Sri Lanka, as there are no major water supply schemes or perennial rivers. Overexploitation, seawater intrusion and persistent pollution of this vital resource are threatening human health as well as ecosystems in the Jaffna Peninsula. Therefore, the main intent of the present paper is to apply geospatial techniques to assess the spatial variation of groundwater quality and availability for the sustainable management of groundwater in the coastal areas. The electrical conductivity (EC) and depth to water (DTW) of 41 wells were measured during the period from March to June 2014, which represents the dry period of the study area. Surface interpolation, gradient analysis, a local indicators of spatial autocorrelations (LISA) and statistical analysis were used to assess the quality and availability of groundwater. The results revealed that the drinking and irrigation water quality in the study area were poor and further deteriorated with the progression of the dry season. Good quality and availability of groundwater were observed in the western zone compared to other zones of the study area. A negative correlation was identified between depth to water and electrical conductivity in the western zone. Hence, relatively deep wells in the western zone of the study area can be used to utilize the groundwater for drinking, domestic and agricultural purposes. The outcomes of this study can be used to formulate policy decisions for sustainable management of groundwater resources in Jaffna Peninsula.
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