The speed of sound and density in binary liquid mixture of diethyl carbonate + benzonitrile, + benzaldehyde have been determined at temperatures 298.15, 308.15 and 318.15 K over the whole composition range. The data have been utilized to estimate the excess adiabatic compressibility (βE), excess intermolecular free length (LfE), excess speed of sound (uE) at the above temperatures. The excess values have been found to be useful in estimating the strength of the interactions in the liquid mixtures.
The densities, viscosities and ultrasonic velocities of binary liquid mixtures of Isopropyl alcohol with acetophenone and methyl isobutyl ketone (MIBK) have been measured at temperatures 298.15 and 308.15 K over the entire range of mole fraction. From these data, acoustical parameters such as adiabatic compressibility (β), free volume (Vf) and free length (Lf) have been estimated using the standard relations. The results are interpreted in terms of molecular interactions present in the mixtures.
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