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The three-dimensional premixed H 2 -O 2 detonation propagation in rectangular ducts is simulated using an in-house parallel detonation code based on the second-order space-time conservation element and solution element (CE/SE) scheme. The simulation reproduces three typical cellular structures by setting appropriate cross-sectional size and initial perturbation in square tubes. As the cross-sectional size decreases, critical cellular structures transforming the rectangular or diagonal mode into the spinning mode are obtained and discussed in the perspective of phase variation as well as decreasing of triple point lines. Furthermore, multiple cellular structures are observed through examples with typical aspect ratios. Utilizing the visualization of detailed three-dimensional structures, their formation mechanism is further analyzed.

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In the study, a software program named “SUPER CE/SE” is developed for the simulation of hypervelocity impact problems with large deformations, high strain rates and spall fractures. In the software program, an Eulerian method consisting of an improved CE/SE (Space-time Conservation Element and Solution Element Method) scheme is used. A void growth model which takes the Bauschinger Effect (BE) into account and a newly proposed front tracking method are adopted in the simulation. The formation and propagation of a crack is described by a newly developed automatic crack growth algorithm. Numerical simulation of spall fracture in a plate when impacted by a spherical projectile at a velocity of 6.0 km/s is carried out. The numerical results are in qualitative agreement with the corresponding experimental data. It turns out that the BE has obvious influence on the length of the crack and better agreement with the experiment is obtained when the BE is considered. It is also validated that the newly proposed front tracking method is feasible and reliable for representing the cracks in the problems with large deformation and high strain rates. According to those research results, it is proved that the software program SUPER CE/SE is robust and effective in the simulation of hypervelocity impact problems.

Carbon-encapsulated iron-based alloy nanoparticles with a core-shell structure were prepared by detonation decomposition of nitrate complex explosives containing multi-metallic ions. The size and magnetic properties of the as-prepared composite particles were revealed by X-ray powder diffraction, transmission electron microscopy, energy dispersive X-ray detector and magnetic measurements. Results showed that the different sizes of the ferronickel and ferrocobalt nanocrystal core and the thickness of the carbon shell could be yielded by adjusting the component materials of the explosives. The composite particles had a gamma- or alpha- ferronickel or bcc-ferrocobalt nanocrystal core with a coating of graphitic carbon layers. Magnetic measurements indicated these composite nanoparticles were superparamagnetism at the room temperature, with some variation in the values of saturation magnetization, remanences and coercive forces.