Droplet motion control on slippery liquid-infused porous surfaces (SLIPS) that mimics the peristome surface of Nepenthes alata has promising applications in the fields of energy, lab-on-a-chip device, etc., yet is limited due to the difficulty in regulating its wettability. In this work, topologies with specific functions from natural creatures, for example, grooved structures of rice leaf and wedge-shaped structures of shore bird beak with droplet transporting capability were integrated with the SLIPS. Three-dimensional topological SLIPS was fabricated on metal substrates using laser milling followed by alkaline oxidation. Fabricated rice leaflike grooved nanotextured SLIPS can properly shape the droplet footprint to achieve a sliding resistance anisotropy of 109.8 μN, which is 27 times larger than that of a natural rice leaf and can therefore be used to efficiently and precisely transport droplets; wedge-shaped nanotextured SLIPS can confine the droplet footprint and squeeze droplet to produce a Laplace pressure gradient for continuous self-driven droplet transport. The created surfaces can manipulate droplets of acid, alkali, and salt solutions. The proposed concept is believed to have potential applications for condensing heat transfer and droplet-based lab-on-a-chip devices.

Slippery liquid-infused porous surfaces (SLIPS) with micro-/nanostructures inspired by the Nepenthes pitcher plant exhibit excellent characteristics in terms of liquid repellency, selfhealing, pressure tolerance, and so forth. In particular, stable bubble transport on SLIPS can be achieved when the surface is submerged in water. However, more precise and sophisticated bubble manipulations on SLIPS still remain challenging. In this research, a three-dimensional topological SLIPS combined with a submillimeter rice leaf-like groove array is fabricated to guide the underwater bubble motion precisely. The dynamic behavior and wetting state of bubbles on SLIPS were investigated experimentally. Furthermore, topological SLIPS with different geometric textures were designed and created for sophisticated bubble manipulations, such as fast bubble directional transport and collection. The results indicated that a lubricant with low surface tension and low viscosity could improve the adhesion force to bubbles and the transport velocity of bubbles, simultaneously. The current findings are helpful to deepen the cognition of interaction between bubbles and SLIPS and to promote their wide applications in the field of smart bubble manipulation and catalytic chemistry.

Spontaneous droplet transport without mass loss has great potential applications in the fields of energy and biotechnology, but it remains challenging due to the difficulty in obtaining a sufficient driving force for the transport while suppressing droplet mass loss. Learning from the slippery peristome of Nepenthes alata and wedge topology of a shorebird beak that can spontaneously feed water against gravity, a combined system consisting of two face-to-face hydrophilic slippery liquid-infused porous surfaces (SLIPS) with variable beak-like opening and spacing was proposed to constrain the droplet inbetween and initiate fast droplet transport over a long distance of 75 mm with a maximum speed of 12.2 mm•s −1 without mass loss by taking advantage of the Laplace pressure gradient induced by the asymmetric shape of the constrained droplet. The theoretical model based on the Navier−Stokes equation was developed to interpret the corresponding mechanism of the droplet transport process. In addition, in situ sophisticated droplet manipulations such as droplet mixing are readily feasible when applying flexible 304 stainless foil as the substrate of SLIPS. It is believed that extended research would contribute to new references for the precise and fast droplet motion control intended for energy harvest and water collection devices.

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