This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
The origin of methane and light hydrocarbons (HCs) in natural fluids from serpentinization has commonly been attributed to the abiotic reduction of oxidized carbon by H 2 through Fischer-Tropsch-type (FTT) reactions. Multiple experimental serpentinization studies attempted to identify the parameters that control the abiotic production of H 2 , CH 4 , and light HC. H 2 is systematically and significantly formed in experiments, indicating that its production during serpentinization is well established. However, the large variance in concentration (eight orders of magnitude) is difficult to address because of the large number of parameters that vary from one experiment to another. CH 4 and light HC production is much lower and also highly variable, leading to a vivid debate on potential role of metal catalysts and organic contamination. We have built a dataset that includes experimental setups, conditions, reactants, and products from 30 peer-reviewed articles reporting on experimental serpentinization and performed dimensionality reduction and network analysis to achieve an unbiased reading of the literature and fuel the debate. Our analysis distinguishes four experimental communities that highlights usual experimental protocols and the conditions tested so far. As expected, H 2 production is mainly controlled by T and P though a strong variability remains within a given P-T range. Accessory metal-bearing phases seem to favor H 2 production, while their role as catalyst or reactant is hampered by the lack of mineralogical characterization. CH 4 and light HC concentrations are highly variable, uncorrelated to each other, and much lower than concentrations of potential reactants (H 2 , initial carbon). Accessory phases proposed as FTT catalysts do not enhance CH 4 production, confirming the inefficiency of this reaction. CH 4 only displays a positive correlation with temperature suggesting a kinetic/thermal control on its forming reaction. The carbon budget of some experiments indicates contamination in agreement with available labeled 13 C studies. Salts in initial solutions are possible sources of organic contaminants. Natural systems certainly exploit longer reaction time or other reactional paths to form the observed CH 4 and HC. The reducing potential of serpentinization can also produce intermediate metastable carbon phases in liquid or solid as observed in natural samples that should be targeted in future experiments.
Purpose This paper aims to describe the “InDO: Institute Demographic Ontology” and demonstrates the InDO-based semiautomated process for both generating and extending a knowledge graph to provide a comprehensive resource for marginalized US graduate students. The knowledge graph currently consists of instances related to the semistructured National Science Foundation Survey of Earned Doctorates (NSF SED) 2019 analysis report data tables. These tables contain summary statistics of an institute’s doctoral recipients based on a variety of demographics. Incorporating institute Wikidata links ultimately produces a table of unique, clearly readable data. Design/methodology/approach The authors use a customized semantic extract transform and loader (SETLr) script to ingest data from 2019 US doctoral-granting institute tables and preprocessed NSF SED Tables 1, 3, 4 and 9. The generated InDO knowledge graph is evaluated using two methods. First, the authors compare competency questions’ sparql results from both the semiautomatically and manually generated graphs. Second, the authors expand the questions to provide a better picture of an institute’s doctoral-recipient demographics within study fields. Findings With some preprocessing and restructuring of the NSF SED highly interlinked tables into a more parsable format, one can build the required knowledge graph using a semiautomated process. Originality/value The InDO knowledge graph allows the integration of US doctoral-granting institutes demographic data based on NSF SED data tables and presentation in machine-readable form using a new semiautomated methodology.
Abstract-The international Group on Earth Observations focus relevant assets -anything from actual sensors and data
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Copyright © 2025 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.