The sensitivity of chitosan to environmental conditions and processing conditions can stress its structure and cause degradation of this polymer on various application carriers. The stability of chitosan in a designed textile structure of standard polyester fabric with chitosan was analysed in a multiple washing process with a standard detergent by studying the properties before and after 10 washing cycles. The chitosan was coated on standard and alkali treated polyester fabrics. Washing was performed with an ECE A reference detergent at 60 °C according to the Standard protocol HRN EN ISO 6330 in 10 cycles. The washing stability of chitosan onto polyester fabrics was monitored by a staining test, zeta potential, breaking force, breaking elongation, pilling propensity, touch, whiteness, moisture transport, antimicrobial activity and morphological features. The staining test confirmed the wash stability of chitosan coated on alkali hydrolised polyester fabrics, while the chitosan coated on standard polyester fabric disappeared. Zeta potential proved to be the significant parameter for determining chitosan` stability. The tensile properties of fabric samples were harmonised with other characterisation parameters. Coating of polyester fabric with chitosan increased the elasticity of all samples. The antimicrobial activity of polyester fabrics coated with chitosan against Staphylococcus aureus was reduced by 20% after 10 washing cycles. All the characterisation parameters proved that polyester fabric as a chitosan carrier should be surface modified for designing a stable bioactive textile structure of chitosan and polyester.
To improve the ability of the rice husk to purify colored wastewater, effluent from the alkaline scouring of cotton yarn was used immediately after the scouring (without cooling and additionally added chemicals) in order to remove the non-cellulosic silicon-lignin shield from the rice husk’s surface. This rice husk, with 93.8 mg/g adsorption capacity, behaves similarly as the rice husk treated with an optimized alkaline scouring recipe consisting of 20 g/L NaOH, 2 mL/L Cotoblanc HTD-N and 1 mL/L Kemonecer NI at 70 °C for 30 min with an adsorption capacity of 88.9 mg/g of direct Congo red dye. Treating one form of waste (rice husk) with another (effluent from the alkaline scouring of cellulosic plant fibers), in an effort to produce a material able to purify colored effluent, is an elegant environment-friendly concept based on the circular economy strategy. This will result in a closed-loop energy-efficient process of the pre-treatment of cotton (alkaline scouring), modification of rice husk using effluent from the alkaline scouring, dyeing cotton fabrics and cleaning its colored effluents with modified rice husk without adding chemicals and energy for heating.
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