The origin of the inconsistency in the erosion phenomena of fluorocarbon polymers between a ground-based atomic-oxygen test environment and the low Earth orbital space environment has been investigated. A detailed experiment was performed in order to study the effect of the high-energy component in the atomic-oxygen beam pulses on the erosion. The experiment was carried out with the combination of a polymer-coated quartz crystal microbalance and a high-speed chopper wheel installed in a laser-detonation atomic-oxygen facility. It was clearly observed that the mass-loss rates of both polyimide and fluorocarbon polymers depend on the impact energy of atomic oxygen. However, the energy dependence is more significant on the fluorocarbon polymer compared with that on polyimide. Collisions of atomic oxygen with translational energies higher than ∼5 eV induce a significant mass loss on the fluorocarbon polymer. These experimental findings agree with earlier measurements of the volatile products released during hyperthermal O-atom bombardment, and they are consistent with theoretical calculations on related systems. It is concluded that the difference in the collision energy distribution of atomic oxygen between laboratory and space environments is the major reason for the difference in erosion yields measured in the two environments.

The contribution of extreme ultraviolet (EUV) and vacuum ultraviolet (VUV) from a laser-sustained plasma on mass loss phenomenon of fluorinated polymer in the ground-based laser-detonation atomic oxygen (AO) beam source was evaluated. The AO beam and EUV/VUV from an oxygen plasma were separated by a high-speed chopper wheel installed in the beam source. Mass changes of fluorinated polymer and polyimide were measured from the frequency shift of the quartz crystal microbalances during the beam exposures. It has been made clear that the fluorinated polymer is eroded by EUV/VUV exposure alone. In contrast, no erosion was detected for polyimide by EUV/VUV alone. The AO-induced erosion was measured for both materials even without EUV/VUV exposure. However, no strong synergistic effect was observed for the fluorinated polymer even under the simultaneous exposure condition of AO and EUV/VUV. Similar results were observed even in the simultaneous exposure condition of AO (without EUV/VUV from the laser plasma) and VUV from the 172 nm excimer lamp and D2 lamp. These experimental results suggest that the primary origin of the accelerated erosion of fluorinated polymer observed in the laser detonation AO source is not EUV/VUV from the laser-sustained plasma.

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