Hexagonal GaN is grown on (0001) sapphire substrates using an atmospheric pressure organometallic vapor phase epitaxy method. We investigate the influences of the initial treatment of sapphire substrate, such as initial nitridation and low-temperature GaN buffer layer deposition, upon the surface morphology and crystallinity. The thermal stability of grown GaN layers is also investigated using a thermal etching process in a H2 atmosphere in order to obtain the information concerning the surface polarity of GaN(0001) layers. When sapphire substrates are initially nitrided, highly crystalline GaN layers with large hexagonal facets are obtained and its surface appears to be (0001)N. On the other hand, the deposition of a thicker buffer layer on the nitrided sapphire substrates improves the surface morphology, and the surface polarity of the mirror surface appears to be (0001)Ga. The initial nitridation of sapphire substrates and the GaN buffer layer deposition are considered to be important processes from viewpoints of the (0001) surface polarity.
High-quality GaAs epilayers with dislocation densities of 1.2×106 cm−2 on (100)Si substrates have been obtained by insertion of an InGaAs strained interlayer combined with thermal cycle annealing instead of strained layer superlattices. All the layers were grown by low-pressure metalorganic vapor phase epitaxy. The threading dislocation density near the surface of 4 μm thick GaAs was measured by plan-view transmission electron microscopy. The threading dislocation density was found to be very sensitive to the In composition of the interlayer and the specifics of thermal cycle annealing.
A Monte Carlo simulation of electron transport in electric and magnetic fields was performed to analyze experimental data of the electron temperature T e and electron number density n e measured in a magnetic neutral loop discharge (NLD) plasma driven in Ar at 0.13 Pa. T e and n e in the vicinity of the substrate holder were measured with a triple probe, and their radial profiles had peaks at different radial positions.The simulation reproduced these peak positions well under the chosen boundary condition that the electron reflectivity of the side wall was lower than that of the reactor ceiling and the substrate holder. It was explained that the T e peak was formed by high-energy electrons transported from the neutral loop along a separatrix of the quadrupole magnetic field and that the n e peak consisted of electrons undergoing reciprocating motion between the reactor ceiling and the substrate.
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