The Tropical Rainfall Measuring Mission (TRMM) Multisatellite Precipitation Analysis (TMPA) provides a calibration-based sequential scheme for combining precipitation estimates from multiple satellites, as well as gauge analyses where feasible, at fine scales (0.25° × 0.25° and 3 hourly). TMPA is available both after and in real time, based on calibration by the TRMM Combined Instrument and TRMM Microwave Imager precipitation products, respectively. Only the after-real-time product incorporates gauge data at the present. The dataset covers the latitude band 50°N–S for the period from 1998 to the delayed present. Early validation results are as follows: the TMPA provides reasonable performance at monthly scales, although it is shown to have precipitation rate–dependent low bias due to lack of sensitivity to low precipitation rates over ocean in one of the input products [based on Advanced Microwave Sounding Unit-B (AMSU-B)]. At finer scales the TMPA is successful at approximately reproducing the surface observation–based histogram of precipitation, as well as reasonably detecting large daily events. The TMPA, however, has lower skill in correctly specifying moderate and light event amounts on short time intervals, in common with other finescale estimators. Examples are provided of a flood event and diurnal cycle determination.

Abstract. The Total Carbon Column Observing Network (TCCON) produces precise measurements of the column average dry-air mole fractions of CO 2 , CO, CH 4 , N 2 O and H 2 O at a variety of sites worldwide. These observations rely on spectroscopic parameters that are not known with sufficient accuracy to compute total columns that can be used in combination with in situ measurements. The TCCON must therefore be calibrated to World Meteorological Orga-

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The Climate Absolute Radiance and Refractivity Observatory (CLARREO) mission will provide a calibration laboratory in orbit for the purpose of accurately measuring and attributing climate change. CLARREO measurements establish new climate change benchmarks with high absolute radiometric accuracy and high statistical confidence across a wide range of essential climate variables. CLARREO's inherently high absolute accuracy will be verified and traceable on orbit to Système Internationale (SI) units. The benchmarks established by CLARREO will be critical for assessing changes in the Earth system and climate model predictive capabilities for decades into the future as society works to meet the challenge of optimizing strategies for mitigating and adapting to climate change. The CLARREO benchmarks are derived from measurements of the Earth's thermal infrared spectrum (5–50 μm), the spectrum of solar radiation reflected by the Earth and its atmosphere (320–2300 nm), and radio occultation refractivity from which accurate temperature profiles are derived. The mission has the ability to provide new spectral fingerprints of climate change, as well as to provide the first orbiting radiometer with accuracy sufficient to serve as the reference transfer standard for other space sensors, in essence serving as a “NIST [National Institute of Standards and Technology] in orbit.” CLARREO will greatly improve the accuracy and relevance of a wide range of space-borne instruments for decadal climate change. Finally, CLARREO has developed new metrics and methods for determining the accuracy requirements of climate observations for a wide range of climate variables and uncertainty sources. These methods should be useful for improving our understanding of observing requirements for most climate change observations

Winds derived from analyzed geopotential height fields are used to study quasi‐horizontal mixing by the large‐scale flow in the lower stratosphere during austral spring. This is the period when the Antarctic ozone hole appears and disappears. Trajectories are computed for large ensembles of particles initially inside and outside the main polar vortex. Mixing and transport are diagnosed through estimates of finite time Lyapunov exponents and Lagrangian dispersion statistics of the tracer trajectories. At 450 K and above prior to the vortex breakdown: Lyapunov exponents are a factor of 2 smaller inside the vortex than outside; diffusion coefficients are an order of magnitude smaller inside than outside the vortex; and the trajectories reveal little exchange of air across the vortex boundary. At lower levels (425 and 400 K) mixing is greater, and there is substantial exchange of air across the vortex boundary. In some years there are large wave events that expel small amounts of vortex air into the mid‐latitudes. At the end of the spring season during the vortex breakdown there is rapid mixing of air across the vortex boundary, which is evident in the mixing diagnostics and the tracer trajectories.