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This study investigated the isotopic composition of daily rainfall in Johannesburg from November 2016 to October 2018. The moisture sources and trajectories for rainfall events of extreme isotopic signatures were deduced using the Hybrid Single Particle Lagrangian Integrated Trajectory model (HYSPLIT). The results from time series and regression analysis show temperature and amount effects, with low coefficient of determination (R2) values of 0.21 and 0.12, respectively. The rainfall with amounts of <20 mm yielded a meteoric water line (MWL) with a slope of +6.9 and deuterium excess (d-excess) of +11.9‰. Rainfall with amounts of ≥20 mm had slope and d-excess values of +8.2 and +18.6‰, respectively. The lower slope in rainfall of <20 mm indicated the preferential occurrence of sub-cloud re-evaporation on light rainfall. Considering the lack of re-evaporation in heavy rainfall (≥20 mm), its slope and d-excess were approximated to those of incoming or in-cloud moisture prior to condensation. Therefore, a high d-excess of +18.6‰ in incoming moisture indicates evaporation that mainly occurs under warm sea surface temperature and low relative humidity. HYSPLIT shows that the moisture for the most depleted and the most enriched rainfall originates in the higher latitudes but differs in trajectory. The moisture for the most depleted rainfall had long residence in the higher latitudes following a semi-direct trajectory to Johannesburg, over the Atlantic and Indian Oceans. The most enriched rainfall followed a curved anticlockwise trajectory with long residence in the lower latitudes over the Indian Ocean. Circulation of saturated moisture over the warm Indian Ocean leads to a loss of light isotopes, thereby enhancing enrichment in the moisture that moves further inland. HYSPLIT indicated the importance of atmospheric conditions along the moisture trajectory on the signature of Johannesburg rainfall.

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Environmental isotope tracers were applied in the Upper Crocodile River Basin, Johannesburg, South Africa, to understand the groundwater recharge conditions, flow mechanisms and interactions between surface and subsurface water. Stable isotope analysis indicated that recharge into the fractured quartzite aquifer occurs through direct mechanisms. The high variability in the stable isotope signature of temporal samples from Albert Farm spring indicated the importance of multiple samples for groundwater characterization, and that using a single sample may be yielding biased conclusions. The observed inverse relationship between spring discharge and isotope signature indicated the traces of rainfall amount effect during recharge, thereby suggesting piston groundwater flow. It is deduced that a measured discharge value can be used in this relationship to calculate the isotopic signature, which resembles effective rainfall. In the shallow alluvial deposits that overlie the granitic bed-rock, piezometer levels and stable isotopes revealed an interaction between Montgomery stream and interflow, which regulates streamflow throughout the year. This suggests that caution should be taken where hydrograph separation is applied for baseflow estimates, because the stream flow that overlies such geology may include significant interflow. The hydrochemistry evolution was observed in a stream fed by karst springs. As pH rises due to CO2 degassing, CaCO3 precipitates, thereby forming travertine moulds. The values of saturation indices that were greater than zero in all samples indicated supersaturation by calcite and dolomite and hence precipitation. Through 14C analysis, groundwater flow rate in the karst aquifer was estimated as 11 km/year, suggesting deep circulation in karst structures.

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