No abstract

Knowledge of thermodynamic properties as well as parameters such as energy density and power flow is important for modeling thermal plasmas of fluoroalkylamine-air mixtures. In this paper, these thermodynamic properties of fluoroalkylamine-air mixture plasmas are calculated in a temperature range of 500 K to 20,000 K at atmospheric pressure and local thermodynamic equilibrium (LTE). The Gibbs free energy minimization method is used to determine the chemical equilibrium compositions of the plasmas that are needed to calculate the thermodynamic properties. These thermodynamic properties are then used to calculate the energy density and power flow of these plasmas. The variation of the energy density is related to the variations of the density and mass enthalpy. We notice that, this energy density increases with the percentage of air in the mixture for temperatures higher than 7000 K. The power flow, which depends also on density, enthalpy mass and sound speed, increases with the percentage of air in the same temperature range. Energy density and power flow results show that increasing air percentage in the mixture can be more interesting for damaging gaseous chemical species such as CF 2 , CO, HCN, and HF appearing at low temperatures with high concentrations.

No abstract

Knowledge of air-water vapor mixtures thermal plasmas thermodynamic properties is important to estimate the performances of electrical arc cutting in this gas by a circuit breaker. In this paper, air-water vapor mixtures thermal plasmas thermodynamic properties are calculated in a temperature range from 5000K to 30000K. The calculations are carried out by supposing local thermodynamic equilibrium at pressure of 1; 5 and 10 atm. The obtained results show the influence of the water vapor initial proportion but also that of the pressure on these plasmas thermodynamic properties.

No abstract