To understand the role of water mains in lead and iron release following lead service line (LSL) replacement, samples were collected from the tap water of 28 homes in Halifax, N.S., after a minimum 6‐h stagnation. In full replacements, average lead concentrations in service lines connected to cast‐iron mains with three different maintenance conditions—pigged, pigged and lined, and not pigged or lined—were 31.5±11.0, 3.3±2.3, and 3.7±2.7 μg/L, respectively, compared with 0.58±0.2 μg/L for ductile‐iron mains. In partial replacements, average lead concentrations were 63.09±30.9, 14.60±2.9, and 6.82±3.3 μg/L, respectively, for the three cast‐iron main conditions, compared with 8.5±3.1 μg/L for ductile‐iron mains. Adsorption of lead on iron corrosion scales dissolved or dislodged from tuberculated mains could account for the higher lead release observed. In this study, full replacement LSLs connected to ductile‐iron mains had the lowest lead concentrations.

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The number and complexity of natural organic matter (NOM) species limits identification of individual NOM compounds. The objective of this study was to employ several characterization techniques (resin fractionation, high performance size exclusion chromatography (HPSEC), and strategic UV254 absorbance) to samples from seven surface water sites in North America, and overcome the shortfalls of each tool. Resin fractionation indicated the samples were all high in hydrophobic acids (HOA), hydrophilic neutrals (HIN) and hydrophilic acids (HIA). Site B was the only site where HIAs were the highest NOM contributors. In the HPSEC analysis, each fraction exhibited a particular molecular weight (MW) range: 100-300 Da (HIN), 1-2 kDa (HOA), and the HIA fractions exhibited MWs between these two ranges. Strategic UV254 measurements were taken at two sites to supplement the HPSEC results, and determine the difference in UV absorbance per unit dissolved organic carbon (SUVA value). Most fractions showed SUVA values of approximately 5 L/mg-m; however, the hydrophilic bases and hydrophobic neutral fractions could not be accurately evaluated due to the very low DOC concentrations for these two fractions (< 0.2 mg/L). These methods are complimentary NOM characterization techniques, and the combined methodology addresses the analytical limits of each tool.

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