A B S T R A C TIn this study, ultraviolet (UV) irradiation followed by chlorination was employed for reclaimed water disinfection. In order to reduce trihalomethanes (THMs) from reclaimed water, suspended TiO 2 (10 mg/L) was added as photocatalyst in UV process to enhance the removal of THM precursors. Reduction of UV absorbance in 254 nm (UV 254 ), dissolved organic carbon (DOC), and THMs formation was analyzed under different experimental conditions (exposure time, pH, TiO 2 doses, and TiO 2 forms). Excitation-emission matrix spectra technology was also used to investigate the changes of dissolved organic matters properties during UV and UV-TiO 2 process. Expansion of irradiation time resulted in a remarkable decrease in UV 254 and THM yields, but showed few influence on DOC removal. THMs yield decreased more than 50% with pH increased from 5 to 9 and rise in TiO 2 dosage also presented a positive effect on photocatalytic disinfection. In addition, a dramatic increase in removal rates of UV 254 , DOC, and THMs was observed when TiO 2 doses were increased from 3 to 15 mg/L. In terms of TiO 2 form, suspended TiO 2 exhibited a better removal capacity on UV 254 , DOC, and THMs by contrast with TiO 2 coated on granular active carbon.