Four types of rigid polyurethane-polyisocyanurate foams (RPU/PIR) were obtained. Three of them were modified by powder fillers, such as cinnamon extract (C10 foam), green coffe extract (KZ10), and cocoa extract (EK10) in an amount of 10 wt %. The last foam was obtained without a filler (W foam). The basic properties and thermal properties of obtained foams were examined. All foams were subjected to degradation in the climatic chamber acting on samples of foams in a defined temperature, humidity, and UV radiation for 7, 14, and 21 days. The physico-mechanical properties of foams were tested. The compressive strength of degraded foams after 7, 14, and 21 days was compared with the compressive strength of nondegraded foams (0 days). The chosen properties of degraded foams, such as cellular structure by scanning electron microscopy (SEM) and changes of chemical structure by FTIR spectroscopy were compared. The obtained foams were also subjected to degradation in a circulating air dryer in an increased temperature (120 °C) for 48 h. Additionally, W, C10, ZK10, EK10 foams were placed in a soil environment and subjected to 28 days biodegradation process. The biochemical oxygen demand (BOD), the theoretical oxygen demand (TOD), and the degree of biodegradation (Dt) of foams were determined in this measurment. Test results showed that the compressive strength of foams decreased with the longer time of foam degradation in the conditioner. The foam subjected to degradation darkened and became more red and yellow in color. The addition of natural compounds of plant origin to foams increased their susceptibility to biodegradation.
In this study, natural extracts of plant origin were used as anti-aging compounds of biodegradable polymers. Coffee (0.5–10 wt%), cocoa, or cinnamon extracts were added to the polylactide matrix. The obtained materials were subjected to an accelerated aging process (720, 1440, or 2160 h) at 45 °C and 70% relative humidity under continuous UV radiation. The effectiveness of the tested extracts was compared to a commercially available anti-aging compound, 2 wt% of butylated hydroxytoluene. Visual evaluation, scanning electron microscopy, melt flow rate, thermogravimetry, differential scanning calorimetry, tensile strength, and impact tensile tests were performed. We show that the use of smaller amounts of tested extracts is particularly advantageous, which do not adversely affect the properties of polylactide-based materials at low contents. At the same time, their effectiveness in stabilizing tested properties during the accelerated aging process is mostly comparable to or greater than the reference compound.
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