This study investigated the concentrations and congener profiles of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) in intake source water (source water) and tap drinking water (tap water) of drinking water treatment plants (DWTPs). In order to have a better understanding on the influence of atmospheric PCDD/F deposition on drinking water, PCDD/Fs in the ambient air of a DWTP (DWTP-LN) were measured and both dry and wet deposition on the water treatment facilities were assessed. The results of this study indicated that the mean PCDD/F concentration in tap water (0.0039 pg WHO-TEQ/L) was found to be approximately 55% of magnitude less than that in source water (0.0086 pg WHO-TEQ/L). In addition, the total deposition flux (dry + wet) of PCDD/Fs entering the DWTP-LN was 27.0 ng I-TEQ/m 2 -year, and wet and dry deposition contributed approximately 12.0% and 88%, respectively. It reveals that dry deposition is more important than wet deposition of PCDD/Fs in the ambient air of DWTP-LN. Atmospheric deposition of PCDD/Fs will increase the level in source water of DWTP-LN up to 8.91 × 10 -3 pg I-TEQ/L, which is approximately 92% of the PCDD/Fs in source water. If a removal efficiency of 87% is achieved by conventional treatment processes including coagulation, flocculation, sedimentation and rapid sand filtration, the water after treatment may increase 1.16 × 10 -3 pg I-TEQ/L, which is approximately 43% of the concentration level in tap water. These results indicate that in the DWTP-LN, the influence of atmospheric deposition of PCDD/Fs on the drinking water is of great significance, and water treatment facility with a cover is suggested.
Responses of Selenastrum capricornutum to cadmium in a chemostat are evaluated under various test conditions defined by the nitrogen to phosphorus ratio, phosphate strength, dilution rate, and ethylenediaminetetraacetic acid content. Based on the test results, these parameters were optimized to achieve superior test sensitivity. This continuous system was also modified to allow testing on a weekly basis. The performance of the modified testing technique was evaluated, employing six different metal toxicants. Compared with batch test results reported by other researchers and our own experiment, the continuous test achieved superior sensitivities and reproducibility. The test method presented in this study is believed to be an ideal technique both for research and regulatory purposes.
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